15 graduates made their way to Clausthal-Zellerfeld and celebrated the 60th anniversary of the handing over of the diploma at the Technische Universität Clausthal
no distance is too far for Clatusthal graduates to come back to their university to celebrate the 60th diploma anniversary. "Your coming is a sign of high esteem and solidarity with Clausthal University of Technology," said Vice President Prof
Christian Bohn at the ceremony in the auditorium in his address to all the jubilarians
1963 was a very special year for the then Clausthal Mining Academy
which was named "Technical University" from that time on
It was also 60 years ago that the first building on the then-new campus in the Feldgraben area
There was a spirit of optimism among the students and professors
"The years of personal and professional development in Clausthal meant a lot to him," said Dr.-Ing
looking back on the time on behalf of the graduating class of 1963
He also reminded his fellow students of old Clausthal traditions after the final exams: "It was 60 years ago that the coachman Stümmel picked us up after the last exam and drove us to a merry drink." In addition to their studies
many students had to earn extra money during the semester break and worked in the iron and steel industry
The rule was: "Work as many shifts and as many holidays as possible
You can recover during the semester." The students lived privately with the local people
The attachment to the people and the place was quite strong
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A steam train travels through the Harz mountains where the trees are destroyed by the bark beetle and drought, near Schierke, Germany, Wednesday, July 26, 2023. (AP Photo/Matthias Schrader)
Ranger Marion Petrik holds spruce bark beetles during a bark beetle monitoring at the Lower-Saxony state forests in a forest of the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. The tiny insects have been causing outsized devastation to the forests in recent years, with officials grappling to get the pests under control before the spruce population is entirely decimated. (AP Photo/Matthias Schrader)
Employees cut a tree infested with bark beetles in a forest of Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
Dead trees stand in Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Friday, July 28, 2023. (AP Photo/Matthias Schrader)
Burrows created by spruce bark beetles course across the inner side of bark pulled from an infested spruce tree in a forest in Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
A car passes dead trees in Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Friday, July 28, 2023. (AP Photo/Matthias Schrader)
Spruce bark beetles lie in a trap during bark beetle monitoring by employees of Lower-Saxony state forests, in a forest of the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
Spruce trees felled due to infestation by spruce bark beetles lie in the Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
Dead trees stand in Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
Media officer Michael Rudolph shows burrows created by bark beetles at the inner side of bark pulled from an infested spruce tree in a forest in Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
Forest contractor Heiner Schulte removes a felled tree infested with bark beetles in a forest of Lower-Saxony state forests at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
Marion Petrik, a forest ranger of Lower-Saxony state forests, checks a trap used to monitor European spruce bark beetles in a forest at the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
CLAUSTHAL-ZELLERFELD, Germany (AP) — Nestled in the spruce trees in the Harz mountains of northern Germany is a bark-eating pest not much bigger than a sesame seed.
Known as “book printers” for the lines they eat into the bark that fan out from a single spine resembling words on a page, these eight-toothed beetles have always been part of the local forest. Officials expect the bugs to typically kill a few spruces each summer as they find suitable trees to lay their eggs — they burrow into the tree’s cambium, or growing layer, hampering it from getting the nutrients it needs to survive.
Ranger Marion Petrik holds spruce bark beetles during a bark beetle monitoring at the Lower-Saxony state forests in a forest of the Harz mountains near Clausthal-Zellerfeld, Germany, Thursday, July 27, 2023. (AP Photo/Matthias Schrader)
“Since 2018, we’ve had extremely dry summers and high temperatures, so almost all trees have had problems,” said Ahrenhold. Spruce trees in particular need a lot of water so having less of it weakens their defenses, and they’re not able to produce their natural tree resin repellent, he said.
And even though the beetles tend to target weakened trees, in dry years the population can reproduce so much “that the beetles were even able to attack healthy spruce in large numbers,” he said. “In some regions there are now no more spruces.”
Experts say there’s no easy solution, but forest managers work to remove trees that might be susceptible to beetles as early as possible and use pesticides where they’re needed.
Michael Müller, the Chair of Forest Protection at the Technical University in Dresden, said there are “very strict requirements for the use of pesticides” which can be very effective in getting rid of the bugs, although the chemicals are sometimes frowned upon for their potentially harmful environmental side effects.
“It’s of course preferable to take the raw wood out of the forest and send it for recycling or to store it in non-endangered areas outside the forest,” he said, but noted that requires a separate logistical operation. On trees that are still standing, he said, it’s not really possible to remove the beetles.
Müller added that forest conservation measures can “sometimes take decades from being implemented to taking effect” and other factors, like storms and drought, and other species, such as game and mice that can also hamper plant growth, are potentially more damaging to the forest in the long run than the bark beetle.
But he said that conservation efforts are limited by external factors, like the changing climate. “After all, we can’t irrigate the forests,” he said.
In the longer term, mixing other tree species into the forest could be a solution, Ahrenhold said. “It makes sense to plant other conifers that can cope better with these conditions, especially on south-facing slopes and on very dry soil,” he said.
Having too many spruce trees in the Harz is a result of centuries of planting big concentrations of the tree, according to Richard Hölzl, an environmental historian at the University of Goettingen and at Five Continents Museum in Munich.
“Clausthal-Zellerfeld is one prime example of a mining area in the Harz where they very early on tried to establish artificial reproduction for spruce to have it for mining construction works,” said Hölzl.
Officials realized by the 19th century that planting just one type of tree over and over again wasn’t a good idea ecologically, but “the economy countered that realization because spruce was such an attractive species,” he said. Spruce was the preferred tree for industrial forestry, paper mills and pulp.
Still, without the warmer and drier weather from climate change, the bark beetles wouldn’t be flourishing in all that spruce.
“There is a long, long prehistory, but there’s also the (climatic) change now,” said Hölzl. “We can’t really blame our forefathers for that.”
Volume 3 - 2024 | https://doi.org/10.3389/fnuen.2024.1414964
In the search for a repository site for high-level radioactive waste in Germany
the perception of safety and trust in the actors are central to public acceptance
methods of safety assessment and the role of uncertainties need to be addressed
there is a need for indicators that are suitable both for assessing the long-term safety of repositories and for communicating with the general public
there is a requirement to communicate uncertainties in an accessible manner
The TRANSENS project provides basic research in nuclear waste management (NWM) and utilizes a transdisciplinary approach: Non-experts who are not directly affected by the site selection process and who have no stated interest in NWM are involved in the research process
A series of four transdisciplinary workshops was specifically designed to explore the perspectives of individuals with a high level of disciplinary knowledge but no system knowledge of NWM
Participants were selected from doctoral students in science and technology who had no prior knowledge in this area
Two of these workshops address the questions stated above and are presented here
The article describes the considerations underlying the workshop planning and implementation phases
and the content developed in the workshops on indicator selection and visualisation of uncertainties
The participants compiled a list of desirable indicator properties
which showed a high degree of congruence with the relevant literature
administer and assess uncertainties shows similarities with the approach followed by the German implementer and complements it with an interactive visualisation
Transdisciplinary work is resource-intensive and its use in a research context must be carefully considered for each individual application
A transdisciplinary approach was successfully used for the purposes of method validation
method optimisation and the development of disciplinary impulses
An application of transdisciplinary approaches for optimising the Safety Case of nuclear repositories is feasible
The research was motivated by the requirements for transparency and public participation laid down in the German Site Selection Act: Information obtained in the course of the site selection process must be made publicly available in order to ensure that the public is kept fully and systematically informed at an early stage about, i. a., the status of its realisation and its likely impacts (Deutscher Bundestag, 2017)
The wording of the regulations is broad and leaves room for interpretation
it is understood that the information to be provided includes the results of long-term safety analyses and the methodology used to demonstrate safety
Although not explicitly stated in the legal text
it is implied that relevant data should be prepared in such a way that it can be understood without expert knowledge
The results of the remaining two workshops are presented and discussed here
and the questions they sought to address were: Which indicators should be used to assess (long-term) repository safety
How can these indicators and their associated uncertainties best be communicated to the general public
The two workshops are jointly presented by a member of the TRANSENS research team (Martina Heiermann) and one of the workshop participants (Vinzent Olszok)
After explaining the motivation for transdisciplinary research
the planning and implementation processes of the workshops are described
The results achieved by the workshop participants are presented
Selected results are discussed in order to demonstrate the application of transdisciplinary processes to method validation
method optimisation and generation of disciplinary impulses
although the circumstances of each project and group of participants need to be considered individually
non-experts can provide both fresh impetus to disciplinary research and legitimisation in socio-technical contexts
There are several taxonomies that allow distinction between different bodies of knowledge. TRANSENS most commonly uses the “three types of knowledge that science should provide to sustainable development” (ProClim, 1997): Systems knowledge
knowledge about the current situation; target knowledge
knowledge about the situation as it should be; and transformation knowledge
knowledge about the transition from the current situation to the target situation
Interactions are aimed at accessing and integrating the relevant types and bodies of knowledge
while engineering and natural science topics form a significant part of their scope
This process is fundamentally different from many other applications of transdisciplinary workshops
where the participants with their types of knowledge emerge from the existing problem field
the questions or challenges are formulated together
and there are no specific expectations regarding the results
Epistemic gain was not the goal of the workshops, nor is it a reasonable expectation for any transdisciplinary work, as Drögemüller and Seidl (2024) note. Scholz and Steiner (2015) distinguish four functions of transdisciplinary processes: Societal capacity building
analytical mediation and legitimising by informal power
analytical mediation is the primary concern
and the two workshops discussed here dealt exclusively with analytical mediation
• Method validation: Are the presented paradigms
will participants without systems knowledge create and outline methods similar to those already established in the expert community
• Stress test: If invited to critique the presented paradigms
do participants identify any weaknesses that are currently not addressed
Which aspects and perspectives are of interest to the participants
• Technical impulse: Are participants able to transfer their disciplinary knowledge to a new context and use this to provide input in terms of improving established methods
the researchers’ objectives became more refined so that their expectations were quite clear before the workshops commenced
the participants reported that the same was not true for them: Prior to the workshops
they were not able to form any specific expectations due to the brevity of the information given in the promotional materials
The aims and methods of the workshop remained quite unclear to them
the participants were not sure whether the main objective was to generate new knowledge or to educate the participants
their roles were not defined until the workshops started
they merely expected to join a discussion group on an interesting but rather unfamiliar topic
Based on the need to address potential arguments from “difficult stakeholders” as well as the objectives formulated above
it was decided that the prospective participants in the transdisciplinary process should have a high level of education in science and technology
but no system knowledge in the field of NWM
the concept of indicators plays a fundamental role
Indicators are parameters that signal certain conditions
Obtaining the information that certain conditions have been reached (or passed) allows for the indirect observation of complex processes or conditions that cannot be measured directly
Examples from other sciences can be used to illustrate the concept
in climate research: climate is a complex state
arrived at through superposition of many processes
and as such not directly measurable; whereas indicators such as precipitation
temperature and hurricane frequency each contribute to defining the climate
time scale and processes relevant in repository safety are much further removed from the everyday experience of the public
it is more difficult to explain the use of indicators for assessing the long-term safety of repositories in a comprehensible manner to persons without prior knowledge: The challenge is to make terms such as “radioactivity flux from the geosphere to the biosphere” or “swelling pressure of the backfill” (to name but two examples for such indicators) more accessible
to convey a basic understanding of processes that are of relevance for their estimation
and to provide context to make the assessment period of a million years more relatable
The two workshops discussed here were to address the question of which indicators are suitable for assessing repository safety and
for communicating with the non-scientific public
Of particular interest was the use of graphs to communicate uncertainties
The participants’ high level of education notwithstanding
the workshops are examples of transdisciplinary work: Their lack of system knowledge
the broader context of the different workshop series and the specific requirements of the research question have to be taken into account
different workshop methods had been tried out
and the plenary discussion proved to be a popular and fruitful method
several methods considered during the planning phase of the third and fourth workshops
as was a practical exercise on understanding scientific graphs
the technical work was carried out in plenary discussions
preceded in several cases by a short pause for reflection or by short impulse presentations
As these changes to the schedule were not initiated by (or even discussed with) the participants
we do not consider these workshops to be co-designed
The participants were given the following tasks:
Which indicator(s) would you use to demonstrate repository safety
Which sources of uncertainties are conceivable
and which categorisation would you suggest for addressing uncertainties in the Safety Case
How should information about uncertainties be communicated
How can uncertainties be presented so that comprehensibility and complexity appear well balanced
The questions were formulated at a rather abstract level
The participants were familiar with terms like “indicators” and “uncertainties” from their own everyday experience
The basic approach in conducting the workshops was to impart only absolutely necessary system knowledge on the subject of nuclear waste disposal in short introductions of approx
This was to minimise influencing of the participants by the workshop organisers
Participants should draw on their experiential knowledge as well as expertise from their respective disciplines to complete the tasks
They should be restricted as little as possible in their work
moderation of the discussions was exercised with great restraint
The aim of these measures was to reduce the potential for bias introduced by the workshop organisers
whether workshop participants or organisers
worked together as a team with common goals
This fundamental attitude is also reflected in the participants’ self-assessment
in which objectivity and solution-orientation play a key role
From the participants’ perspective
the group’s homogeneity was perceived as beneficial in a number of ways: A common technical vocabulary allowed for fast-paced discussions
and ideas could be quickly sketched out without having to explain the technical background at length
Discussions were characterised by an error culture that allowed for the admission of mistakes without any negative implications
ideas could be expressed without fear of criticism and could serve as nuclei for in-depth consideration and development by the group
the different professional specialisations and personal perspectives of the participants came into play
which they recognised as central to the development of the content
the participants did not run out of ideas or perspectives; on the contrary
the facilitators had to intervene several times in order to bring the discussion to a close
the participants viewed the good error culture and the appreciative behaviour in general as crucial for the success of transdisciplinary work
more so than in other collaborative work situations (e.g.
as the transdisciplinary approach forced them to engage with ideas and topics that did not correspond to their own area of expertise and took them out of their comfort zone
The following analysis is based on the facilitators’ and observers’ notes
anecdotal selection of statements and results
They reflect the opinions and knowledge of the workshop participants
No audio recordings were made and there is no transcript of the discussions
As unclear or incorrect statements were repeatedly challenged by other participants
the absence of disagreement (verbal or non-verbal) was interpreted as agreement
statements made by one participant were taken to reflect the opinion of the whole group
Whenever unanimity is explicitly mentioned
all participants had signalled their agreement
The topic of knowledge transfer and science communication was of particular interest to the participants
since teaching and thesis supervision are often among the tasks of doctoral students and thus part of their everyday lives
The focus of the discussions was often not on the content to be communicated
other aspects of communication were more closely considered
with the intention of making communication more efficient
work on the question “What indicators would you use to show the safety of the repository?” began with a comment about trust and perception
and other meta-level aspects such as context
level of complexity and level of detail were closely intertwined with the message content throughout the discussion
Participants agreed and accepted that in terms of effectiveness
goal would be to make the sender’s and receiver’s messages congruent (“they hear what I say”)
there are two major challenges: technical expertise and trust in the senders
Some tasks were therefore implicitly addressed at two levels:
• Under which conditions will the message be perceived by the recipients in the first place and then considered worth dealing with
• How must the content be selected and prepared so that the interested public can understand the information and draw valid conclusions
The participants did not elaborate on the issue of trust
but it was implied in all discussions that trust in science as such
trust in scientists as fallible human beings
and/or trust in the site selection process is lacking amongst members of the general public
The possibility of instrumentalising information was illustrated with the example of monitoring: “Why are you measuring this
Are you not sure [of your design’s reliability]?” Instead of promoting a sense of safety through regular measurements
clever framing could turn the message into the opposite and promote mistrust and anxiety
Target group-oriented communication was viewed sceptically: “Target group-oriented communication means that everyone else falls by the wayside”
the necessity was seen: “You cannot please everyone”
The group was also divided on the issue of data availability: On the one hand
open access to all data was seen as a necessary prerequisite for transparency and meaningful participation; on the other hand
there was concern that de-contextualised information could be misunderstood or misused
An interesting question that arose from the discussion on uncertainties was formulated as follows: “Are people supposed to actively seek information or are they “bombarded” like during a commercial break on TV”
The discussion on motivation was not pursued further
but was touched upon several times in relation to entertainment
which participants believed to have promoted acceptance of nuclear energy production in the 1950s and 1960s
The suggestions of talk shows and satirical programmes as potential means of communication also point to passive reception of information through entertainment
The participants first looked at communication in general - the discussion on target group-oriented communication described above also took place within the scope of this task - and at contextualisation in particular
Communication should provide spatial and temporal context to make it more relatable: Where is surface contamination unlikely
As one participant stated: “I care about the next 1,000 years
I do not care who owns my property after that”
Other examples of contextualisation were given: Reference values and limits - how are they determined
Trustworthiness - who collected the data and made the calculations
A brief discussion arose about how views and evaluations of indicators can vary over time and depending on the social context
This stretched the arc even further and embedded the use of indicators in the overall context of society and science
Participants gave two examples: One possibility is that new knowledge will give the indicator a new significance “like the atmospheric CO2 concentration
after its role in the greenhouse effect was better understood”
Another possibility is that society’s values and (risk) perceptions may change over time: “the cloning of non-human mammals is becoming more acceptable”
Participants identified a number of properties that a suitable indicator should possess:
• Relevance: The indicator has to be effective and specific (“the indicator must represent what we want to represent”)
• Communicability: The statements made by the indicator must be easy to convey
This also includes comparability with experiences from personal everyday life
In order to address a range of target groups effectively
the use of several different indicators should be considered
• Uncertainties must be taken into account and communicated
Since they increase in both space and time
the indicators “must be adjusted for time”
selected for their suitability in regard to the time frame under assessment
• Measureability: Participants mentioned (environmental) monitoring several times
implying that measurability is a desirable characteristic
• Practicability: This characteristic was mentioned
the term can mean that the derivation of the indicator should not be too complicated or computationally time-consuming
Workshop participants often expressed repository safety in terms of a probability without specifying the event in question (although two possible interpretations were given as “something goes wrong” and “I get cancer”)
the concept of “risk” was not considered very suitable for public communication purposes
since statistical relationships were deemed difficult to convey
This is particularly relevant here because several interrelated probabilistic processes had to be considered (probability of exposure; probability of developing cancer after exposure)
Several indicators already established in the expert community were discussed
Participants offered suggestions for indicators not currently established that might be useful in communicating with the public:
• Impact: The indicator either directly quantifies the impact of the repository at the surface or allows for an estimate of this impact
how “impact” is defined and how it should be quantified
it was suggested that the area affected by exposure should be estimated
The basic approach proposed by the group was to prepare and make available all indicators that are suitable in principle
but to select only a few for communication in the mass media
the group did not specify which indicators or types of indicators they considered most appropriate for this task
participants were asked to reflect on possible categorisations of uncertainties with the intention of comparing their results and motivation with the established method
The first step was to compile sources of uncertainty
The top entry in the list was “time”
such as the evolution of society and the political framework
One idea that had already occupied the group in connection with the formal site selection procedure was that new findings or changed social values might lead to a re-evaluation of facts (see 3.2.1)
Other sources referred to modelling in the broadest sense
parameter variability and numerical effects
Humans as a source of error were mentioned
as was the availability and comprehensibility of the documentation produced
environment and economy were named as further sources of uncertainties
Despite the previous discussion on the instrumentalisation of information (see above)
participants agreed that uncertainties needed to be disclosed as an integral part of all communications
Different categorisations of uncertainties were explored
different dimensions of uncertainties were considered: their cause
Example for proposed categorisation of uncertainties
The question of a motivation for such a categorisation was not raised by the group; it was only mentioned in an aside that the categorisation of uncertainties “influences how we deal with them”
without this point being taken up further in the discussion
The discussion on the topic of uncertainties nevertheless focused on a related question: Does the decision for a certain categorisation of uncertainties change the safety evaluation of the repository
Acknowledging this led to a further question: Does the categorisation influence future actions
the group of participants was unanimous in coming to a positive answer
The main line of reasoning was that the prioritisation of the categorisations has an influence on the subsequent treatment of the problem; in this respect
the categorisations are important for future outcomes and may therefore trigger different responses
participants’ attention was deliberately drawn to digital formats in order to ensure that they would consider the additional tools and opportunities offered by digitalisation
While the researchers intended this to refer to the use of digital tools within the formal framework of the Safety Case
the participants interpreted the question much more broadly
In line with the general approach to workshop facilitation
the group was allowed to pursue its discussion
the use of a whole range of different formats for different conditions and purposes was discussed
Examples are educational videos for school lessons; webinars and Q&A sessions with experts for the interested public; podcasts
talk shows and documentaries on streaming platforms as easily accessible information sources; graphic novels and educational game apps for playful learning of younger people
Participants identified the following challenges for successful communication of uncertainties:
• Adaptation to the needs of many different target groups: Level of detail
wording and format must be tailored to the audience and their (presumed) background knowledge
The need for granular adaptation was expressed by one participant’s comment that “15-year-olds communicate differently than 25-year-olds”
referring to the preferred social media platforms of different age groups
• Trustworthiness of the format: TV documentaries were perceived as more valuable than videos on internet platforms; print media in turn as more trustworthy than TV
There are personal preferences for information channels and the use of a few conventional formats may fail to reach a significant portion of the population
• Short attention span: Intensive engagement with a complex topic like NWM requires time and concentration
This was seen as problematic in a time when an endless number of short messages and videos compete for attention
must counteract problems such as loss of knowledge and disinterest
The same questions will be asked many times by the public
The participants identified various instruments that support communication:
• Interactivity: The user’s ability to control the level of detail was judged to be of particular importance
• New technologies: The use of virtual reality and artificial intelligence offers new possibilities
to answer questions in an internet forum created for this purpose
• Didactic methods: The importance of graphics was emphasised (“a picture is worth a thousand words”) and various stylistic devices were mentioned
• Contextualisation: Uncertainties should be “embedded in the whole package”
as their relevance only becomes apparent in the context of the specific topic
This includes an appraisal of their impact - or lack of impact - on the safety of the repository
• Framing: Embedding in a narrative involves a selection and evaluation of information and often has negative connotations (“the evil atom”)
suitable framing can also have a mobilising effect: “I would rather click on the page “safety-in-the-repository.de” than on “uncertainty-in-the-repository.de”
In task 4, participants created sketches of graphs showing data with uncertainties. One of these proposals is presented in Figure 2 as an example
Participants’ suggestions for the visualisation of Monte Carlo simulations
(B) area below maximum for five discrete scenarios; (C) maximum plane as interpolation of several scenarios differentiated by a continuous parameter
they could be used to create a 3D surface that encompasses all values resulting from the considered scenarios
Color can be used to encode the probability of values occurring
The participants further discussed the possibility of creating a dimensionless parameter in order to characterize the uncertainties in each scenario
Another participant suggested plotting the curve of maximum doses from all calculated scenarios in an X-Y scatterplot
The presentation is to be in the style of an infographic
Features are to include the use of “yellow barrels” as markers; icons for “a playing family” and “a hazmat suit” to indicate the safe and hazardous dose value ranges
respectively; and the marking of limit and reference values
Such an infographic is to be created for each time of interest
A third suggestion concerned an interactive network diagram (Figure 3)
it is possible to encode continuous or categorical data in five dimensions
Clicking on an uncertainty reveals information about it
while clicking on the link between two uncertainties reveals information about the relationship between them
cross-hatching or colour saturation to add a further dimension to the graphs (e.g.
a graduated colour band representing probability from 0 to 1)
but showed awareness of both the emotional and evaluative effect of colours and potential accessibility issues
Interactive 3D network diagram suggested by workshop participants
Clicking on a marker highlights the uncertainties’ predecessors (P1 - P3) and successors (S1
S2) and opens a context menu with information regarding the selected uncertainty
The results below were selected to provide examples for the application of transdisciplinary methods for method validation
method optimisation and generation of technical impulses
It shows that many of the concepts compiled by the IAEA experts were either explicitly addressed or implied by the workshop participants
Notable exception are properties related to the determination of the indicator value
It was apparent from the discussion that they assumed that this would be unproblematic and relevant methods well-established
Noteworthy is the additional criterion of measurability
The participants repeatedly implied that the indicator should be measurable
implies that the indicator (or the parameter it is directly derived from) is detectable at the Earth’s surface or at least close to the surface
It is conceivable that measurability may be even more important for the general public
who are less familiar with modelling and less trusting of scientists
Whether measurability is technically relevant or useful is besides the point: The decisive factor is that a value perceived as “real” or “true” is available
which can be compared with previous model calculations if necessary
Figure 4. Comparison of indicator properties collected by workshop participants and by IAEA experts. Illustration based on data taken from International Atomic Energy Agency (1994)
Task 4 (see section 3.4) asked participants to prepare sketches of graphs that might help to communicate uncertainties. The discussion of this task was chosen to illustrate the potential adaptation of an existing method for an additional purpose. One of the suggestions made by the workshop participants was the creation of an interactive network diagram as shown in Figure 3
All uncertainties related to the evaluation of repository safety could be represented in a 3D diagram
five categories would be available to encode relevant data
with marker diameter an intuitive choice to represent the impact of the uncertainty on the end result
Predecessor-successor relationships could be easily visualised
The data stored for each uncertainty could be displayed in pop-up windows or tooltips
Although network diagrams are in use for tracking parameter relationships and/or uncertainties
as part of the database maintained by the German implementer
Bundesgesellschaft für Endlagerung mbH
these are designed to facilitate the preparation and review of the Safety Case by experts
They are not suitable for use by non-experts
it should be feasible to extract the relevant information and build an interactive diagram as envisaged by the workshop participants
with one caveat: In order for the size of the bubbles to be a meaningful representation of safety relevance
there must be a method of assessing the impact of uncertainties that is common to all parameters
Task 3 (see section 3.4) asked participants to reflect on the communication of uncertainties
The discussion of this task was chosen to demonstrate the potential for disciplinary impulses
Starting with graphs showing the results of Monte Carlo simulations
the participants discussed the use of the Buckingham Pi theorem to create a dimensionless parameter that would allow the comparison of the uncertainties of different scenarios
The basic requirement for comparability is that the diagrams share a common structure
If the uncertainties contained in each diagram could then be expressed as a single numerical value
the uncertainties of a large number of simulations would be easily comparable
the information content of many complex diagrams could be condensed into a simple bar chart
and would then be easy to convey in public communication
Although the underlying methods and assumptions may be too complex for non-experts to understand
they could be used to effectively illustrate site comparisons
different design concepts and alternative evolutions of the repository
not elaborated further during the workshops due to time constraints
may serve as an example of disciplinary inspiration by persons without systems knowledge
The participants did not offer any preferences regarding the choice of indicator(s) for the safety assessment
they favoured indicators that were directly measurable and could be used to estimate the impact on the surface caused by a loss of containment
Uncertainties should be communicated transparently
Communication with the general public should make use of interactive graphics: The user should be able to adjust the level of complexity and information content as required
Similarities in the backgrounds of the participants helped to deepen the discussions
A greater diversity of perspectives can be achieved by other means
by including participants from different organisations or personal backgrounds
Careful selection of research questions that focus on the interface between science and society
or on a social or societal aspect of the research topic
offers the best chance of producing useful results in science and engineering research
Transdisciplinary research is resource intensive in the planning and implementation phases
Experiments cannot be repeated and results are not amenable to statistical processing
a thorough analysis has to indicate whether a transdisciplinary approach is appropriate for the problem at hand
costly problem with an extremely long time horizon that affects the entire population
The choice of a transdisciplinary approach therefore seemed appropriate and our results confirm this: The content developed by the participants during the workshops was similar to the findings of experts
This supports the plausibility and comprehensibility of the contents and methods under consideration and thus strengthens their legitimacy
The transdisciplinary approach has been shown to be effective in scientific and engineering research for the purposes of method validation
stress testing and technical impulse generation
For future applications of the transdisciplinary approach in natural scientific or engineering research, the theoretical basis and terminology need to be refined and a toolbox of methods should be developed specifically for these applications. On the basis of the ten-step approach Pohl et al. (2017)
specific guiding questions could be formulated to help assess the suitability of research questions for transdisciplinary treatment and to support the planning phases of transdisciplinary workshops
The datasets presented in this article are not readily available because the data contains information which allows the identification of individuals. Requests to access the datasets should be directed to bWFydGluYS5oZWllcm1hbm5AdHUtY2xhdXN0aGFsLmRl
Ethical approval was not required for the studies involving humans because the research is based on workshops offered within the framework of a postgraduate programme
The studies were conducted in accordance with the local legislation and institutional requirements
The participants provided their written informed consent to participate in this study
The author(s) declare that financial support was received for the research
This research was funded by the Federal Ministry for the Environment
Nuclear Safety and Consumer Protection and the Volkswagen Foundation
The authors would like to thank the TRANSENS team
Klaus-Jürgen Röhlig and Marcel Ebeling
The authors declare that the research was conducted in the absence of any commercial or financial relationships that could be construed as a potential conflict of interest
All claims expressed in this article are solely those of the authors and do not necessarily represent those of their affiliated organizations
Any product that may be evaluated in this article
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1The term “experts” is used here in the sense of “individuals with extensive system knowledge”
which includes practice actors and scientists
2The term “citizen” is used specifically in the sense of “any member of the civil society without in-depth knowledge of NWM”
Its use in this text can be considered equivalent to “non-expert” and appears only as part of the title of the Citizens’ Working Group
3The term “scientist” is used in this text to refer to any individual who seeks to advance science, but in particular to those who do so in an academic setting (e.g., universities, research institutes). On the pitfalls of defining the participants in transdisciplinary research, see also Defila and Di Giulio (2018)
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Citation: Heiermann M and Olszok V (2024) Transdisciplinary research on the safety case for nuclear waste repositories with a special focus on uncertainties and indicators
Received: 09 April 2024; Accepted: 23 September 2024;Published: 16 October 2024
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In this work froth flotation studies with LiAlO2 (lithium-containing phase) and Melilite solid solution (gangue phase) are presented
The system was optimized with standard collectors and with compounds so far not applied as collectors
the principle of self-assembled monolayers was introduced to a froth flotation process for the first time resulting in excellent yields and selectivities
a potential shortage of raw materials could threaten supply safety
efficient recovery of lithium from spent LIBs is vital
they have been functionalized for these applications with different molecules
we present here an alternative approach towards froth flotation and compare the behavior of different collectors in an in situ standard flotation to a pre-functionalization approach
the main phase of the ore is Melilite s.s.
there are some impurities such as Merwinite
ATR-IR-Spectra were recorded on an Alpha-T IR (Bruker) with a platinum ATR-unit and diamond crystal
10 w% of organic compound and toluene were refluxed under N2 in a Dean–Stark apparatus for 16 h or stirred at room temperature for 16 h
The remaining solid was washed three times with toluene and dried under high vacuum
The combined toluene solutions were evaporated and non-reacted organic compounds were recovered
Used collector compounds next to sodium oleate
the material was washed with toluene and dried
The combined toluene filtrates were combined and evaporated to dryness to recover the phosphonic acid or phosphate
In all cases both minerals became very hydrophobic to such an extent that froth flotation experiments were not possible
the experiments showed that also at room temperature
a high level of functionalization is feasible
Flotation yield of TTA and TOPO functionalized LiAlO2 (a) and Melilite (b)
Functionalization with LiAlO2 and Melilite s.s.
Self-dehydroxylation on silica under water removing
FT-IR measurement of TTA functionalized LiAlO2 (a) and Melilite s.s
with lithium-containing minerals so far flotation experiments with these collectors
Effect of Collector Dosage on Flotation of LiAlO2 using decyl dihydrogen phosphate.
Effect of Collector Dosage on Flotation of Melilite s.s
it is possible to note that for the flotation of LiAlO2
decyl dihydrogen phosphate has a low selectivity
with a dosage of 300 g/t is about 10% lower than that of LiAlO2
which can be explained again by the fast hydrolysis of the collector
Effect of Collector Dosage on Flotation of LiAlO2 using bis(2-ethylhexyl) phosphate at natural pH
Finally, a standard system was also scaled up in a small flotation machine. The achieved results are shown in Table 2 for LiAlO2 and Melilite s.s
at natural pH by using a small flotation machine
Sodium oleate and LiAlO2 treated in sodium oleate solution
(b) IR spectra of samples obtained after the desorption experiment: stirred at a rate of 500 rpm without washing; stirred at 500 rpm with washing; stirred at 1000 rpm with washing
In summary it was possible to show that LiAlO2 and Melilite s.s
Both standard collectors and compounds not previously used as collectors were investigated
Very good yields and selectivities could be achieved with these collectors after optimization
the principle of self-organized monolayers (SAM) was introduced for the first time in a froth flotation system
The pre-functionalization resulted in a significant improvement compared to the standard
These results will allow a new approach for the separation of different minerals via froth flotation in the future and further studies are currently conducted
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Jaskula, B. W. Lithium. https://pubs.usgs.gov/periodicals/mcs2021/mcs2021-lithium.pdf (2021)
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in SME Mineral Processing and Extractive Metallurgy Handbook (eds R
Speciation of manganese in a synthetic recycling slag relevant for lithium recycling from lithium-ion batteries
A study of the solubility of pure slag minerals
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Sintering and devitrification of glass-powder compacts in the akermanite–gehlenite system
New data on the composition of melilite during solid phase and solid-liquid phase synthesis
Comptes Rendus-Academie Bulgare des Sciences 48
in European Mineral Processing & Recycling Congress
in Adsorption from Aqueous Solutions (ed P
in Adsorption from Solution at the Solid/Liquid Interface (eds G
Mechanisms of alkyl sulfonate adsorption at the alumina-water interface
The quantitative application of infrared spectroscopy to studies in surface chemistry
Surface precipitation of inorganics and surfactants and its role in adsorption and flotation
Chemistry of Flotation (Soc of Mining Engineers of AIME
Revealing water films structure from force reconstruction in dynamic AFM
Sum-frequency vibrational spectroscopy on water interfaces: Polar orientation of water molecules at interfaces
Water adsorption on the α-Al2O3(0001) surface
The chemistry of water on alumina surfaces: Reaction dynamics from first principles
Formation and structure of self-assembled monolayers
targeted drug delivery systems using mesoporous silica nanoparticles: Opportunities & challenges
Mesoporous silica and organosilica nanoparticles: Physical chemistry
Development of silica-based stationary phases for high-performance liquid chromatography
A high temperature capacitive humidity sensor based on mesoporous silica
Functional organophosphonate interfaces for nanotechnology: A review
Reversed active sites boost the intrinsic activity of graphene-like cobalt selenide for hydrogen evolution
Synthesis of alkyl dihydrogenphosphate by the reaction of alcohols and silyl polyphosphate
Enhanced mobility for increasing on-current and switching ratio of vertical organic field-effect transistors by surface modification with phosphonic acid self-assembled monolayer
Facile synthesis of zirconia-coated mesoporous silica particles by hydrothermal strategy under low potential of hydrogen conditions and functionalization with dodecylphosphonic acid for high-performance liquid chromatograph
Straightforward immobilization of phosphonic acids and phosphoric acid esters on mesoporous silica and their application in an asymmetric aldol reaction
Electrochemical stability enhancement of electrochromic tungsten oxide by self-assembly of a phosphonate protection layer
Characterization of functionalized glass and indium tin oxide surfaces as substrates for super-resolution microscopy
Detection of surface silanol groups on pristine and functionalized silica mixed oxides and zirconia
Magnetically recoverable chiral catalysts immobilized on magnetite nanoparticles for asymmetric hydrogenation of aromatic ketones
Self-assembling adhesion promoters for corrosion resistant metal polymer interfaces
Phosphonate coupling molecules for the control of surface/interface properties and the synthesis of nanomaterials
Covalent surface modification of oxide surfaces Angew
Collecting performances and adsorption mechanism of alkylphosphorous esters on cassiterite
Method of beneficiating sulfide and oxide ores of copper
Synergetic effect of a mixture of anionic and nonionic reagents: Ca mineral contrast separation by flotation at neutral pH
adsorption and flotation studies of sphalerite using di(2-ethyl hexyl)phosphoric acid
Spectrophotometric determination of iron species using a combination of artificial neural networks and dispersive liquid–liquid microextraction based on solidification of floating organic drop
Separation and determination of a trace amount of lithium as its complex with 12-crown-4 by means of synergic extraction and flame thenoyltrifluoroacetone photometry
Solvent extraction of lithium from ammoniacal solution using thenoyltrifluoroacetone and neutral ligands
μ-Phenoxide bridged mixed ligand Cu(II) complex: Synthesis
energy frameworks and antimicrobial studies
Molecular information on the potential of europium complexes for local recognition of a nucleoside-based drug by using nanostructured interfaces assembled as langmuir−blodgett films
Surface modifcation via 2-thenoyltrifuoroacetone and the photophysical studies
Solvent extraction of lithium ions using benzoyltrifluoroacetone in new solvents
Enhancing the properties of perovskite quantum dot light emitting devices through grid structures formed by trioctylphosphine oxide
Effective surface ligand-concentration tuning of deep-blue luminescent FAPbBr 3 nanoplatelets with enhanced stability and charge transport
Highly stable all-inorganic perovskite quantum dots using a ZnX2-trioctylphosphine-oxide: Application for high-performance full-color light-emitting diode
Amorphous SiO2 surface models: Energetics of the dehydroxylation process
ab initio atomistic thermodynamics and IR spectroscopic signatures
Thermal stability of phosphonic acid self-assembled monolayers on alumina substrates
Solvent extraction of beryllium from aqueous solutions of mineral acids by alkyl esters of phosphoric acid
Acidic organophosphorus extractants: I: Extraction of lanthanides by means of dialkyl phosphoric acids: Effect of structure and size of alkyl group
A multi-stage process for recovery of neodymium (Nd) and dysprosium (Dy) from spent hard disc drives (HDDs)
Lithium recovery from Li3PO4 leaching liquor: Solvent extraction mechanism of saponified D2EHPA system
and forsterite using sodium oleate as the collector
Enrichment of silicocarnotite from silicocarnotite and gehlenite mixtures using a kerosene-based liquid-liquid separation process
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We thank Petra Sommer from the Institute of Mineral and Waste Processing
Waste Disposal and Geomechanics for analysis
We thank Sebastian Keber from the Institute of Mineral and Waste Processing
Waste Disposal and Geomechanics for his help with flotation experimental design
We thank Thomas Schirmer from the Institute of Disposal Research for discussions
Open Access funding enabled and organized by Projekt DEAL
performed the experiments and were responsible for analytical data preparation
was preparing Elemental Analysis und TGA data
All authors helped in improving the manuscript
The authors declare no competing interests
Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations
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Babette Tonn welcomes and congratulates many deserving participants
there was a lot to celebrate at TU Clausthal's Foundry Technology Colloquium at the Institute of Metallurgy
Sponsorship: 30 years of the Freunde und Förderer der Gießereitechnik an der TU Clausthal e.V
(Friends and Sponsors of Foundry Technology at the TU Clausthal)
Here it's all about attractive student life and a lively network
Research: Innovations and Industry 4.0 - Reports from Industry and Research
Celebrating: Professor Reinhard Döpp on his 90th birthday
Babette Tonn had gathered many friends and supporters of Clausthal University of Technology around her and put together an interesting program:
The crisis as a permanent state - how can the foundry industry become more resilient Dr
Sustainability through innovation management and cooperation Dr
Possibilities of digitalising material information in the foundry Dr
Quality assurance in iron casting Dr Torsten Rieck
FONDIUM Mettmann GmbH Mettmann Wolfgang Baumgart
Faster to better results through digitalisation of simulation Dr
Bocar GmbH Leinfelden-Echterdingen
Understanding core shooting better Rudolf Wintgans
Process-side elimination of step artefacts in 3D-printed moulds and cores Christoph Hartmann
Special features of interface formation in Al-brass composite casting Vanessa Glück Nardi TU Clausthal
The technical presentations also dealt with the significant challenges that are currently affecting us all as well as the view into a digitalized and highly networked future
This was comprehensively confirmed from the point of view of the presenting foundries
lack of skilled workers and so much more cannot be solved ad hoc
but the colloquium always contributes to cultivating and promoting exchange and cohesion
Reinhard Döpp was appropriately honored and celebrated the evening before as a prelude to the Foundry Evening
which the participants will remember fondly
I would like to receive the bi-weekly Foundry-Planet newsletter with all latest news
Plus the special newsletters – all can be cancelled anytime and at no cost
you’d be nothing!” My favourite response: “What makes you think I’m something now
Do you think the chancellor cares if you or I live or die?”
People who make “problematic statements” online would also be screened
The meeting abroad would be a victory for the separatists as it gives the appearance of bilateral negotiations between two heads of state
a veteran of the German automotive industry
recently sat down for an interview to discuss the ideological struggle of the Greens against the automobile—and the consequences for Europe
Spaniel studied chemical engineering in Clausthal-Zellerfeld and mechanical engineering at RWTH Aachen
and worked for many years as a development engineer
He became a member of the German Bundestag in 2017
where he is currently the AfD policy-spokesman for transport
cars with internal combustion engines could continue to be operated in a CO2-neutral way
the supply network would already exist via the filling stations and the problem we have today—of spiralling energy costs for e-car owners—would not weigh so heavily
the Greens and their stalwarts in the other parties strictly reject e-fuels
This shows me that their reasons are ideological
private transport will become more and more expensive
The freedom we have experienced in recent decades to decide for ourselves when
and how we get around will no longer be affordable for many people
unless we can effectively oppose this policy throughout Europe
one must develop the most efficient and resourceful infrastructure
road transport remains essential for mobility
Directing investments into infrastructure and road transport leads to efficient mobility and great economic benefit
The second point is simply to foster openness to technology
we will recognise synthetic fuels as CO2-neutral
There will be competition for the best technology
and the electric car will also come under cost and reputational pressure
This will create the climate of innovation that we need
I personally believe that the internal combustion engine will ultimately prevail
The FDP has even written the preservation of the combustion engine
they cannot—or will not?—come good on the commitment
If an open-minded approach to technology and e-fuels had been more than just a campaign slogan
A representative of the French transport committee
answered that they had not evaluated the draft decisions in detail
It was assumed that the Germans knew what they were doing
Germany is increasingly becoming a transfer society
Transfer societies tend to nationalise their industries; and that is exactly what the European Union is actually striving for: more state control
The nationalisation of industry will lead to greater centralisation at the EU level
which is definitely in the interest of the Brussels bureaucrats
and not necessarily in the interest of the liberal European parties
You have to look at the future of the car industry in different ways
which will relocate to countries with better conditions
This will lead to massive job losses in Germany and Europe
but not necessarily to negative business results for the respective corporations
Then there are the many supplier companies
They will not be able to simply relocate abroad
even more of the wealth creation in Europe will take place in the non-manufacturing sector
This in turn will lead to high economic volatility
and one of the pillars of the economy will be research and development
But you can only develop things whose production processes you understand
And if the production processes no longer take place in Europe
it will become a big problem to maintain Europe’s GDP through services
Great Britain has already experienced something similar
The countries mentioned have the advantage that energy costs are lower there than in Germany
That means they can benefit to some extent from relocations within Europe
But they are equally affected by corporate relocation outside Europe
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We present in-situ self-diffusion experiments in solids
which were carried out by Focussing Neutron Reflectometry on isotope multilayers
This new approach offers the following advantages in comparison to classical ex-situ measurements: (1) Identification and continuous measurement of a time dependence of diffusivities
(2) significant reduction of error limits of diffusivities
and (3) substantial reduction of the necessary experimental time
yet unknown self-diffusivities in amorphous germanium are measured at various temperatures quasi-continuously
A significant decrease of diffusivities as a function of annealing time by one order of magnitude is detected that is attributed to structural relaxation accompanied by defect annihilation
In metastable equilibrium the diffusivities follow the Arrhenius law between 375 and 412 °C with an activation energy of Q = (2.11 ± 0.12) eV
The diffusivities are five orders of magnitude higher than in germanium single crystals at 400 °C
The drawback of all tracer methods (radiotracer
NR etc.) is that the diffusion process cannot be monitored in-situ
In order to extract diffusivities after tracer deposition
diffusion annealing and tracer redistribution
the sample under investigation has always been cooled down to room temperature in order to freeze diffusion before time-consuming analysis is done
For several advanced metastable materials (amorphous semiconductors
nano-materials) an in-situ recording of diffusivities directly during diffusion and annealing with high temporal resolution in the minutes range is highly interesting
It would allow identifying and quantifying the modification of time-dependent diffusivities due to structural relaxation
Such effects are often masked by ex-situ experiments due to heating and cooling periods and a limited number of data points (diffusivities per time interval)
it is not necessary to complexly adjust the sample after each annealing step
This will drastically enhance the exactness of the determination of reflectivities and reduce error limits of diffusivities as well as experimental time
A significantly higher number density of diffusivity values
can be reached and activation energies might be determined more precisely
This enables a quasi-continuous in-situ detection of self-diffusivities directly during annealing
This new approach offers the following advantages: (1) Identification and continuous measurement of time dependent diffusivities
(2) significant reduction of error limits of diffusivities and activation energies
(3) substantial reduction of the necessary experimental time and (4) direct measurement of diffusion during diffusion controlled structural re-arrangements (e.g
we present and discuss first experiments on in-situ monitoring of self-diffusivities for the model system amorphous germanium in order to illustrate the efficiency of the method
Classical prototypes are silicon and germanium due to their simple tetrahedral short range structure
The knowledge of diffusion processes in such materials is relatively limited
The high covalent bond energy leads to low self-diffusivities below the crystallization temperature
the intrinsic metastability has the consequence that annealing (e.g
during preparation or microstructural tailoring) at elevated temperatures may lead to crystallization processes
an experimental access to such systems is complicate
Such effects will lead to time-dependent diffusivities that have to be identified
is kept fixed and the other quantity is varied
The Selene setup allows a variation of both parameters at the same time
The wavelength is determined by time-of-flight and the scattering angle with a position sensitive detector
This experimental arrangement improves the intensity at the sample significantly so that the reflected intensity can be measured continuously and binned down to 1 min resolution
Annealing was performed in a specially designed rapid thermal annealing setup (AO 500
extremely fast heating rates are possible which allow one to reach temperatures up to 500 °C in less than 30 s
For the in-situ NR experiments the annealing setup was optimized for use in the neutron beam by separating the heating chamber from the control unit and equipping it with two sapphire windows for entrance and exit of the neutron beam
The temperature of the sample was recorded during the NR measurement by a RT100 thermocouple located at the sample position and controlled by a PID controller
Grazing-Incidence X-ray Diffractometry (XRD) for structural characterization of the samples before and after annealing was carried out using a Panalytical Empyrean diffractometer (CuKα
incidence angle α = 1°) at the Institut für Nichtmetallische Werkstoffe
Grazing incidence X-ray diffraction patterns of [73Ge (14 nm)/natGe (14 nm)] × 10 multilayers at different temperatures
The patterns are shifted in intensity along the ordinate for clarity
r = 28 nm is the 73Ge/natGe bilayer thickness and Dav is a time averaged diffusivity as given by
This low error limits in D will also lead to a reduced error in the activation energy of diffusion (see below)
The time dependence of the instantaneous D is described by a first order reaction as
It can be transformed into eq. (3) by inserting eq. (4) into eq. (2)
A significantly improved fit of the experimental data assuming a time-dependent diffusivity was found for all temperatures under investigation in the temperature range between 370 and 412 °C
This has the consequence that a decrease of diffusivities is observed
This annihilation process occurs on a time scale of the relaxation time τ
thermal equilibrium diffusion takes place intrinsic to the metastable amorphous structure
The overall thickness of the Ge multilayer as determined from the Bragg peak position varies non-systematically (statistically) during annealing by a maximum value of about 0.5%
This is not supporting the assumption of a large densification of the amorphous structure
this effect can definitely contribute to the decrease of diffusivities observed
a further advantage of in-situ experiments over ex-situ experiments becomes clear
Time-dependent diffusivities with very short relaxation times of several minutes as found here cannot be identified properly by an ex-situ experiment
often the effect of relaxation is averaged out and effective diffusivities are determined
Only the quasi-continuous recording of several hundred of reflectivity patterns and hence Bragg peak intensities as a function of time allows to exactly detect the time-dependence of diffusivities on the given time scale
Note also that in-situ experiments lead to a substantial reduction of experimental time
several hundred reflectivity patterns are recorded
each corresponding to an instantaneous diffusivity in a single experiment lasting some hours
This is not possible by ex-situ experiments where each diffusivity has to be measured separately
The consequences are a significant reduction of error limits and a proper identification of time-dependent diffusivities as mentioned
The diffusivities in metastable equilibrium D = De obtained at various temperatures are plotted in Fig. 4 as a function of inverse temperature. The diffusivities obey the Arrhenius law
Also shown is the diffusivity for a sample pre-annealed at 425 °C for 5 min (blue open circle)
This clearly shows that pre-annealing at higher temperatures eliminates structural relaxation effects
we presented in-situ self-diffusion experiments in solids based on Focussing Neutron Reflectometry
Amorphous germanium was used as a model system
Diffusivities were measured quasi-continuously during isothermal annealing at different temperatures
This new approach has the advantage of a significant reduction of error limits of diffusivities while at the same time a substantial reduction of the necessary experimental time is achieved
The method also allows identification and continuous measurement of time-dependent diffusivities
which is not possible during ex-situ studies
The self-diffusivities in amorphous germanium follow the Arrhenius law between 375 and 412 °C with an activation energy of Q = (2.11 ± 0.12) eV with absolute values five orders of magnitude higher than in germanium single crystals at 400 °C
Phase Transformations in Materials (Wiley-VCH Verlag GmbH & Co
Self-Diffusion in Amorphous Silicon by Local Bond Rearrangements
Contributions of vacancies and self-interstitials to self-diffusion in silicon under thermal equilibrium and nonequilibrium conditions
Application of the Nuclear Reaction Analysis Online Technique to Study the Diffusion of Deuterium in Metals
Self-diffusion in intrinsic germanium and effects of doping on self-diffusion in germanium
Nitrogen self-diffusion in silicon nitride thin films probed with isotope heterostructures
Similarity between the Properties of Native Point Defects
Silicon self-diffusion in isotope heterostructures
Self-and foreign-atom diffusion in semiconductor isotope heterostructures
Self-diffusion in crystalline silicon: A single diffusion activation enthalpy down to 755 °C
Structural relaxation and self-diffusion in covalent amorphous solids
Nitrogen diffusion in amorphous silicon nitride isotope multilayers probed by neutron reflectometry
How to measure atomic diffusion processes in the sub-nanometer range
Self-diffusion in germanium isotope multilayers at low temperatures
Grain Boundary Self-diffusion in Fe Films with a Stable Nanostructure
The study of self-diffusion in crystalline and amorphous multilayer samples by neutron reflectometry
Iron self-diffusion in amorphous FeZr/57FeZr multilayers measured by neutron reflectometry
Atomic transport in metastable compounds: Case study of self-diffusion in Si−C−N films using neutron reflectometry
Implementation and experience on the TOF-reflectometer Amor
Nuclear Instruments and Methods in Physics Research Section A: Accelerators
Focusing specular neutron reflectometry for small samples
The physics and applications of amorphous semiconductors (Acad
Physics of amorphous semiconductors (World Scientific [u.a.]
Alloy negative electrodes for Li-ion batteries
Technology and Applications of Amorphous Silicon (Springer
Short range atomic migration in amorphous silicon
Atomic transport during solid-phase epitaxial recrystallization of amorphous germanium
Tetrahedrally Coordinated Random-Network Structure
On the crystallization of amorphous germanium films
The crystallization of amorphous germanium films
Annealing and crystallization of amorphous germanium thin films
Structural Relaxation and De-Relaxation Phenomena in Amorphous Ge Films upon Irradiation with Short and Ultrashort Laser Pulses
Structural relaxation and crystallization of amorphous Ge films
Structural relaxation and defect annihilation in pure amorphous silicon
Structural relaxation in ion-damaged amorphous germanium
Defect production and annealing in ion-implanted amorphous silicon
Calorimetric evidence for structural relaxation in amorphous silicon
An intrinsic stress scaling law for polycrystalline thin films prepared by ion beam sputtering
Preparation of Sn-doped In2O3 (ITO) films at low deposition temperatures by ion-beam sputtering
An X-ray photoelectron spectroscopy study of the HF etching of native oxides on Ge(111) and Ge(100) surfaces
A study of contaminant overlayer on Ge(l00) surface using kinetic resolved XPS
Secondary ion mass spectrometry: a practical handbook for depth profiling and bulk impurity analysis (Wiley
Crystallization kinetics of amorphous germanium
In situ x-ray diffraction study of metal induced crystallization of amorphous germanium
Single crystalline SiGe layers on Si by solid phase epitaxy
Epitaxial growth of germanium thin films on crystal silicon substrates by solid phase crystallization
and noble gases on the crystallization of amorphous Si layers
Self-diffusion and defect annihilation in nanocrystalline Fe films probed by neutron reflectometry
Migration and annihilation of non-equilibrium point defects in sputter deposited nanocrystalline alpha-Fe films
Correlation between self-diffusion in Si and the migration mechanisms of vacancies and self-interstitials: An atomistic study
Study of effective Debye temperature for germanium
On the solubility and diffusivity of the intrinsic point defects in germanium
Elucidating the atomistic mechanisms driving self-diffusion of amorphous Si during annealing
Mechanism of boron diffusion in amorphous silicon
Intrinsic and dopant-enhanced solid-phase epitaxy in amorphous germanium
In Kuech T Handbook of Crystal Growth: Thin Films and Epitaxy
Download references
This work is based upon experiments performed at the Swiss spallation neutron source SINQ
The research project has been supported by the German Research Foundation under the contract Schm1569/29-1
Dörrer (TU Clausthal) for doing the SIMS analysis
We acknowledge support by Open Access Publishing Fund of Clausthal University of Technology
Laboratory for Neutron Scattering and Imaging
Institute for Applied Materials (IAM) and Karlsruhe Nano Micro Facility (KNMF)
analysed data and wrote parts of the manuscript
did the technical supply and supervision of NR experiments and wrote the program for NR data extraction and analysis
supplied the XRD equipment and supported XRD data analysis
performed and analysed the X-ray photoelectron spectroscopy measurements
Publisher’s note: Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations
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DOI: https://doi.org/10.1038/s41598-018-35915-1
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See the Program here: Information and Exchange - Classical Topics - Digitalization - Machine Learning - Foundry Night
which showed us that high flexibility and innovations are essential for our economic success
the first top events in 2023 are now coming up
The 4th Molding Materials Forum 2023 at Clausthal University of Technology will once again offer a platform for information and exchange on diverse areas of mold and core production
The focus will be on classic topics as well as digitalization or the use of machine learning for process design
An attractive program of lectures and large exhibitor areas will provide the opportunity to find out about new trends and developments and to discuss them in more detail in personal meetings
The Foundry Meeting in the historic Glückauf Hall rounds off the event
Together with the entire organization team
Babette Tonn at the Clausthal University of Technology
looks forward to welcoming you to Clausthal-Zellerfeld and experiencing an exciting Molding Materials Forum together with you
See here the current event program as of January 2023:
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a power electronics provider for the marine industry
has won a contract to deliver the single drives for shaft…
Fast-growing energy demand is driving the need for technical support and guidance in new locations
Belgium-based offshore installation services company DEME has completed the acquisition Havfram
Jan De Nul has kicked off the installation campaign of the monopile foundations for RWE’s Thor offshore wind farm
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Now is the ideal time for hiking across Europe – and these glorious trails are all reachable without flying
Spooky strolling amid atmospheric mountainsDistance 58 milesSuggested number of days Five or six
where better to hike than a land of wicked witches and creepy fairytales
The Harz Mountains have long been associated with German folklore and the region is hugely atmospheric in autumn
when smoke starts twirling from the chimneys of half-timbered houses
The moderate-grade Harzer-Hexen-Stieg (Harz Witches Trail) runs along forest tracks through Harz national park and can be walked throughout October
View image in fullscreenThe Waldstätterweg trail has views over Lake Lucerne
Photograph: Caroline Pirskanen/Caroline Pirskanen | Luzern TourismusWhy
Still-accessible mountains and marvellous mistsDistance 71 milesSuggested number of days Three to seven
Switzerland is arguably the world’s best place to hike
Mountain huts close in September and snow can block trails
it’s best to plan day walks and head out only if the weather allows
For a multi-day adventure, Switzerland Tourism’s Chloé Schenkel recommends the Waldstätterweg trail
“It’s one of the safest when it comes to snow conditions,” says Chloé
“and the views and the colours of the trees are breathtaking at the end of October.”
This moderate seven-stage route traces the shore of Lake Lucerne
from the village of Brunnen to the meadow at Rütli
with the dazzling blue water a constant companion
elegant promenades and trails through chestnut woods to link lakeside settlements
with the exception of the 1,100 metres Bürgenstock cliff path
View image in fullscreenThe Risleten Schlucht waterfall on the Waldstätterweg. Photograph: Armin Ben Wurmser & Tina GerberThe Waldstätterweg has plentiful accommodation, such as the lakeside Hotel Nidwaldnerhof (doubles from €175 B&B) in Beckenried
View image in fullscreenParasol mushrooms (Macrolepiota procera) in Los Alcornocales park. Photograph: Nature Picture Library/AlamyWhy? A newer mountain route that’s warm into winterDistance 68 milesSuggested number of days Six
Autumn isn’t just a good time to walk in Andalucía; it’s arguably the best. The weather stays warm long after winter starts to bite further north. It’s cheaper and less crowded, too.
Read moreThe circular GR141 runs in a loop to the south of Ronda
riverside trails and forests of chestnuts and ancient cork oaks
Along the route are dramatic El Colmenar gorge
whose canutos (deep ravines) shelter unique plants
View image in fullscreenThe view towards Lagkadia in the central PeloponneseWhy
Late autumn colour and excellent quiet trailsDistance 47 milesSuggested number of days Four to seven
The Menalon Trail is officially excellent
It was the first in Greece to be awarded “leading quality” status by the European Ramblers Association
a designation that ensures the route’s high standard and positive impact on local communities
Temperatures are pleasant and autumn colours are glorious well into November in the central Peloponnese
extending the window for long-distance walkers
The trail curves like a question mark in the western shadow of 1,981-metre Menalon
old stone settlements and steep-sided valleys cloaked in woods that glow come autumn
It also passes tavernas offering filling goat stews
You might even catch the Arcadian grape harvest in progress: it can extend into November
trikolonioncountry.gr) and a folklore museum showcasing the village’s jewellery-making heritage
The path’s official website describes the walk in a northward direction, but On Foot Holidays’ self-guided Arcadia trip runs the opposite way
“This makes the most spectacular walk along the Lousios Gorge the grand finale
rather than the start,” says On Foot’s Heather Bamber
which lists accommodation and sells the official trail map
View image in fullscreenSan Gimignano
but with wineDistance 68 milesSuggested number of days Seven
Prices tend to drop considerably in November
View image in fullscreenCabo de São Vicente
Dramatic coast walking in balmy weatherDistance 466 miles totalSuggested number of days At least four
Weaving around the overlooked south-west Alentejo and Vicentine Coast natural park, the Rota Vicentina isn’t just a network of wonderful walking trails, it’s a community triumph
created a decade ago by local businesses seeking to attract sustainable tourism year-round
The complete Rota Vicentina comprises 24 circular day hikes and two 13-stage trails: the 141-mile coastal Fishermen’s Trail and the 163-mile Historical Way
which heads into the mountains and forests
The walking is generally easy and well waymarked
The biggest challenge is choosing which section of which route to do
to busy Lagos on the Algarve’s south coast
it’s possible to walk 75 miles from the fishing village of Zambujeira to craggy Cabo de São Vicente
mainland Europe’s most southwesterly point
View image in fullscreenRocha Negra near Lagos
Photograph: Samuel Foster/AlamyIn autumn there are dolphins to spot offshore and thousands of birds migrating along the eastern Atlantic flyway
The walking is via dunes and herb-infused heathland
the ruined Ribat of Arrifana (an Islamic fortress) and charming villages such as Rogil and Bordeira
Dr. Jürgen Großmann: "Who really read the Paris Climate Agreement?
The Clausthal professors Heinz Palkowski, Karl-Heinz Spitzer, Harald Schmidt and Babette Tonn had invited to the metallurgical colloquium at the TU Clausthal.
Under the motto "Business and Science in Dialogue", former and current Clausthalers as well as experts from various disciplines were able to exchange views on the urgent topics of the time. The topics and strategies in thermochemistry, micro kinetics, metallurgical process engineering, foundry technology and material transformation are, of course, shaped by the current challenges, in particular from the Paris Climate Agreement.
Dr. Matthias Weinberg (2nd from left) was able to impressively point out the path of Thyssenkrupp Steel's steel production towards climate neutrality and Jürgen Großmann (2nd from the right), Georgsmarienhütte Holding GmbH, recognized the noticeable challenges with utmost sensitivity. Industry, like politics, urgently needs to recognize the signs. In Germany, everyone is talking about the climate, but hardly anyone actually knows the contents of the Paris Agreement.
For his services to the foundry industry and foundry chemistry, Dr. Ing. Wilhelm Kuhlgatz (Hüttenes-Albertus Werke) of the Association of Friends and Sponsors of the TU Clausthal, was honored for his merits and received a honorary "Barbara".
Jennifer Maki has been appointed executive director of Vale's Base Metals division after its previous executive director, Peter Poppinga, was named executive director of Ferrous Minerals for the company.
Maki has worked for Vale since 1993, and since January has been the chief financial and administrative officer for Base Metals. She also participated in the management of Base Metals businesses outside Canada.
Maki has an undergraduate degree in business from Queen's University and a postgraduate diploma from the Institute of Chartered Accountants.
After working at PricewaterhouseCoopers for 10 years, Maki joined Vale as assistant controller, holding several positions including vice-president, treasurer and chief financial officer.
She has been a member of the board of commissioners of PT Vale Indonesia Tbk (PTVI) since 2007 and recently became its president commissioner.
As executive director of Vale's Base Metals division, she will be responsible for the company's operations in Sudbury.
In a news release, Vale said Maki has made major contributions to the business, taking "firm action" in cost management and control, in the implementation of funding strategies, in negotiating joint venture agreements in base metals and in the co-ordination of work to resolve issues related to pension funds of Base Metals group companies."
Poppinga studied geology at the Federal University of Rio de Janeiro, Brazil, and has an undergraduate degree in applied geology from the University of Clausthal-Zellerfeld, Germany.
With more than 20 years' experience in iron ore, Poppinga began his career in 1984 at Samitri, an iron and manganese mining company, where he held leadership positions in mine planning, iron ore production, and sales and marketing.
He also held shared responsibility for sales of pellet production at Samarco and was involved in the development of the Chinese iron ore market. He joined Vale in 1999 in the Iron Ore Commercial area, where he held several positions in the company's foreign sales offices, including sales director in New York and Belgium, and chief executive officer of Vale International in Switzerland.
In 2007, after Brazil-based Vale purchased Inco, Poppinga held several corporate positions in Toronto. In 2009, he returned to operations as chief operating officer of Base Metals Operations, Asia & Pacific, based in Australia.
In 2011, he was appointed executive director of Base Metals and IT, leading 16 operating sites around the world and driving major transformations and asset base optimization that turned the business around and delivered improved results.
He is replacing Jose Carlos, whom Vale said left the company to take on new challenges in his career.
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· Information leaks pierce privacy
· Canada 'keen on' China partnership
· PLA beefs up military training system
· Tight air control rules impede private flights
· New policies to boost cross-Straits ties
· Airport adopts new security rule on liquid
· Science post to light the way
· Rebels release Chinese hostages
· Golden-week holiday spells nightmare
which recently moved up to the blue-chip board of the London stock market
accounts for four percent of Kazakhstan’s GDP and is one of the world’s biggest producers of the raw materials that go into steel – a material close to the chief executive’s heart
“My grandfather and father were both steelmakers
and so I became a steelmaker,” he told us in response to emailed questions
“All of my personal targets early on were bound up with that industry
I grew up in the shadow of a steelmill in Germany.”
began his career as an academic at the Technical University of Clausthal-Zellerfeld in the 1970s
before joining steelmaker Ispat International
known for audacious mergers and acquisitions that have put his firm at the top of the global steelmaking tree
for his ability to make decisions on the basis of the big picture and without getting lost in the detail,” Sittard says
unlike those who worry too much about covering their backs.”
Mittal’s family background is in steel
He was the reason I worked for Mittal,” Sittard says
Sittard joined the firm now known as ENRC in 2001
The company began life as a group of assets bought by company founders Patokh Chodiev
Alijan Ibragimov and Alexander Machkevitch during Kazakhstan’s wave of privatisations in the mid-1990s
had a market capitalisation of around $23bn
The three founders each retain stakes of 14.6 percent
while Sittard’s own shareholding is less than three percent
Shares in the company have risen 80 percent since the company floated in London last December
dramatically outperforming the all-share index
Part of ENRC’s success lies in the proximity of Kazakhstan
but while Kazakhstan is happy to supply the building blocks of a new China
“It is not Kazkhstan’s ambition to become like China
It is their (Kazakhstan’s) aspiration to be a modern state modelled on a western country
The country has achieved a vast amount in its 10-15 years of independence and is fast embracing modernity.”
Being at the starting point of a process of industrial growth is what excites Sittard about the raw materials business
“No industry can grow without the use of natural resources,” he said
“This sets the natural resource industry at the beginning of a chain of value creation
and makes it a great place to create as much value as possible.”
China or any of the other metal-producing or consuming parts of the world
Sittard can be found on the ski slopes or the coast
“I have skied every year but one of the 55 since I first started
I ski in Austria where I have a house near where my wife grew up
An outdoor sportsman as well as a mining executive
he is keenly aware that extractive industries take a particularly heavy toll on the natural world
“I am also very conscious of the environmental impact of the work I do and am motivated to minimise the negative impact
mining has had a substantial negative impact on the environment
but it will continue to be a big challenge for everyone in the industry.”
The Supervisory Board of OMV Petrom appointed Christopher Veit as the new Executive Board Member of OMV Petrom responsible for Upstream
In line with OMV Petrom’s articles of association
the appointment is for the remaining term of the mandate granted to Peter Zeilinger
Chris Veit accepted his appointment and will assume the mandate as of October 1
Prior to the Supervisory Board meeting today
Peter Zeilinger waived his mandate as the Executive Board Member responsible for Upstream
His waiver shall become effective on September 30
The Supervisory Board would like to thank Peter Zeilinger for his contribution and his commitment to the success of the company
the Supervisory Board welcomes Chris Veit as the new Executive Board Member responsible for Upstream
Peter Zeilinger holds a Masters degree in Petroleum Engineering from the Technical University of Clausthal-Zellerfeld in Germany
In more than 27 years with the OMV Group he held various technical and management positions in Austria
From 2011 to 2016 he led the Australasia region of OMV in Wellington as Managing Director for OMV New Zealand Ltd and Director of OMV Australia PTY
Peter Zeilinger spent almost 9 years with OMV Petrom in the position of Director Domestic Assets and from April 2016 as Executive Board member responsible for Upstream
During his tenure as member of the Board in OMV Petrom
the Upstream division implemented a number of strategic changes
including regional growth in the Black Sea
divestments of marginal fields as well as modernization and simplification of the production network
Peter Zeilinger is taking over the role as Senior Vice President Exploration
Production & Development in the Head office Vienna
Chris Veit holds a degree in Mechanical Engineering and a Masters degree of Petroleum Engineering of the Mining University at Leoben
He started his career with Schlumberger as wireline engineer and joined 1986 OMV Austria Exploration & Production GmbH in Gaenserndorf as a Production Engineer
He has held various technical positions and subsequently management positions in Libya
Pakistan and as well as in Austria such as the Senior Vice President and Managing Director of OMV Austria Exploration & Production GmbH
he took over the role as Senior Vice President for Exploration
Development and Production to develop and contribute to the evaluation and reorganization of whole OMV Upstream organization
Chris Veit currently represents OMV in several supervisory boards of its subsidiaries and is member of the advisory board of the Department Petroleum Engineering at Mining University Leoben
OMV Petrom is the largest energy company in South-Eastern Europe
with an annual Group hydrocarbon production of 55.4 million boe in 2019
The Group has a refining capacity of 4.5 million tons annually and operates an 860 MW high efficiency power plant
The Group is present on the oil products retail market in Romania and neighboring countries through 802 filling stations
one of the largest listed industrial companies in Austria
and 18.352% is the free float on the Bucharest Stock Exchange and the London Stock Exchange
OMV Petrom is the largest contributor to the state budget
with contributions of 30.4 billion euro in taxes and dividends paid between 2005 and 2019
OMV Petrom has included corporate responsibility principles into its business strategy
the company has allocated approximately 66 million euro to develop communities in Romania
OMV Petrom announced its support for the recommendations issued by the Task Force on Climate-related Financial Disclosures (TCFD) regarding risks and opportunities on climate change
The Nobel Prize is the most prestigious award that can be given to experts in the fields of Chemistry
he left no heirs and most of his fortune was placed into a trust to be used for prizes for those who have excelled in their field
According to the website of The Nobel Prize
only 590 Nobel Prizes have been awarded since 1901
it’s not an easy thing to win the Nobel Prize
but usually only one (or one team) can win
Some candidates are nominated more than once
Arnold Johannes Wilhelm Sommerfeld came up for consideration 84 times but never won
Sommerfeld was born in 1868 in East Prussia and received his Ph.D
in mathematics and physical sciences from the University of Königsberg in 1891
He apparently had a few rowdy college years resulting in a permanent fencing scar on his face from inebriated duels
and remained in the military reserves for the next eight years
he gained his teaching license for high-level mathematics
Sommerfeld’s talents became well known as he advanced
to the chair of the mathematics department at the Bergakademie in Clausthal-Zellerfeld
He also became the editor of the Enzyklopädie der mathematischen Wissenschaften
Sommerfeld later accepted the chair of Applied Mechanics at the Königliche Technische Hochschule Aachen
Germany where he formed his theory of hydrodynamics
Sommerfeld was the director of the Theoretical Physics Institute at the University of Munich
His students at both of those universities included many names well-known in scientific circles
It was at the Königliche that he taught Peter Debye
won the Nobel Prize in Chemistry for his contributions to the study of molecular structure
Heisenberg won the Nobel Prize in Physics in 1932 for the creation of quantum mechanics
Other students from Munich include Wolfgang Pauli
who won the Nobel Prize in Physics in 1945 for his discovery of the “Pauli exclusion principle”
the winner of the Nobel Prize in Physics for his theory of stellar nucleosynthesis in 1967
Because of the caliber of the scientists that could claim Sommerfeld as their mentor
“What I especially admire about you is that you have
pounded out of the soil such a large number of young talents.”
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Mathematician Morris Kline stated of Sommerfeld
that he was an inspiring teacher at the vanguard of relativity
and that he educated the greatest physicists in the first 30 years of the twentieth century
and Nobel Prize winner Max Born noted that Sommerfield took undisciplined but creative minds and helped them realize what they didn’t know as well as fostering the skills and discipline necessary to perform fruitful research
these men were impressed not only with Sommerfeld’s education and knowledge but his teaching abilities as well
many promising scientists in Europe fled Germany
Sommerfeld watched sadly as Germany lost brilliant minds and decided that he must remain and continue teaching
Adolf Hitler appointed his own people who were barely qualified
and Sommerfeld was replaced as Professor of Theoretical Physics by Wilhelm Müller who was an an aerodynamicist and wholly unqualified to hold the post
Sommerfeld continued his work in quantum theory
he co-discovered the Sommerfeld-Wilson quantization rules with Englishman William Wilson
worked with electromagnetism and hydrodynamics
and advanced the information of X-ray wave theory
and his theory of electrons in metals was valuable in the study of thermoelectricity and metallic conduction
Sommerfeld’s nominations for the Nobel Prize can be found listed in the Nomination Archive of the Nobel Prize website
His name was put forward to receive the award for Physics in 1917
Sommerfeld was hit by a truck as he crossed the street — an accident attributed to his diminished hearing in his elder years
Read another story from us: The Genius of Marie Curie was Formed at an Underground Illegal University
Although he never won the Nobel Prize himself
one could say that he won many times through those he educated and inspired
Ian Harvey is one of the authors writing for The Vintage News
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