The man had argued and threatened a neighbor with a knife while they were on the stairs of the apartment building where the two lived
shot dead a 26-year-old Afghan man in Schoenebeck
The man had argued and threatened a neighbor with a knife while they were on the stairs of the apartment building where they lived
the 26-year-old attempted to attack the officers
who later died in hospital,” a police spokesperson said
According to the German newspaper “Magdeburger Volksstimme,” the officers first fired three warning shots
“The weapon was confiscated and the prosecutor’s office is investigating the exact circumstances that led the officer to shoot the 26-year-old,” the spokesperson said
Read also other news on Nova News
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ASHWAUBENON (WLUK) -- Amy Schoenebeck - a Certified Genetic Counselor at Aurora BayCare Medical Center - joined us at the FOX 11 Field House to talk about genetic testing
Schoenebeck recommends that people with the following factors should consider genetic testing:
Schoenebeck notes: "So the process (of genetic testing) is often a blood test
And then essentially they're looking for a mistake - something in a gene that's increasing the risk for cancer
It is not a guarantee that someone is going to get cancer - it's just increasing their risk and then we can be smarter ..
what kind of extra screenings or risk reduction options are available
Cause ideally we want to stop a cancer in the first place
or find it as early as possible so we have the best outcome."
When asked if it's important to talk to a genetic counselor before resting
Schoenebeck responds: "I'm probably biased but I think yes
Ideally we can go over the family history ..
There are some very specific kinda national criteria
Most insurance companies do cover genetic testing
but often they follow those similar criteria
and what would it mean for your family members
So making sure you have the right information to share with them as well as the right health care team."
To learn more about genetic testing at Aurora BayCare you can request an appointment with a cancer specialist by visiting AuroraBayCare.com/appointments
Metrics details
While the trans-isomer usually requires heating at approximately 200 °C to trigger thermal isomerization under racemization to cis-divinylcyclopropane
which then undergoes facile Cope-type rearrangement
the analogous contra-thermodynamic process is herein shown to proceed under Ni(I) metalloradical catalysis under mild conditions without any loss of stereochemical integrity
enabling a mild and stereochemically pure access to seven-membered rings
We herein disclose a metalloradical catalysis mode that is initiated by non-covalent interaction via π-coordination
which leads to reactivity that is fundamentally in contrast to organic free radical reactivity and enables a reversible cis/trans-isomerization of vinylcyclopropanes under chiral inversion
Our preliminary tests with a specific diphenyl substituted vinylcyclopropane indicated a partial isomerization instead of opening
which fundamentally questions the validity of vinylcyclopropanes as mechanistic probes to test for metal-based radical intermediates
neither the factors that dictate isomerization versus opening have been elucidated
nor the wider scope and potential of this reactivity in synthesis
We therefore set out to resolve these fundamental questions with a view to devise a selective and general isomerization for vinylcyclopropanes that proceeds without any loss of enantiopurity
Selective stereoinversion of distal stereocentre
Computational study of reaction pathway and orbital analysis of intermediate (Int2)
Our closer inspection of the absolute stereochemistry of the product revealed that the carbon distal from the vinyl substituent was inverted selectively during isomerization, having generated (R,S)-trans-2 (Fig. 2a)
Ni(I) therefore must have a profound effect on the overall reaction path
in locking the stereocentre adjacent to the vinyl substituent
while also influencing the overall driving force to favour the strained
ring-closed product over ring-opened/rearranged products
the lack of racemization observed under Ni(I)-catalysed isomerization (as opposed to thermal isomerization) means that
although formally in both processes a homolytic scission of the central cyclopropane bond takes place
the Ni-coordination locks one stereocentre through a π–allyl complex
leaving only one centre to rotate (and invert)
Another notable difference to organic free radical reactivity is that addition of an organic free radical
both in terms of strain release and also the resonance delocalization gained through the aromatic substituent
the radical is clearly more stabilized on the Ni-centre in the closed cyclopropane form
in which the vinylcyclopropane serves predominantly as a π-ligand
So called ‘radical clocks’ should hence be used with caution to test for the intermediacy of metal-based radicals
the computed profile also suggests that the Ni(I)-bound cis- and trans-vinylcyclopropanes have only minute differences in energies
which suggests full reversibility of the isomerization process
The equilibrium is shifted ultimately through coordination/decoordination of the Ni(I) so as to reach the overall cis:trans ratio that reflects the inherent cis/trans preference of the substrate itself
the observed ratio indeed matches the substrate’s free energy difference of the cis- and trans-isomer
This suggests that the overall selectivity of the isomerization is readily predictable upon assessment of the inherent energy difference of the cis- and trans-isomer
Our electron paramagnetic resonance (EPR) measurements of 3 itself in dioxane or with added cis-2 substrate gave distinct signals characteristic of the intermediacy of a metal-based radical
While the Ni(I) dimer 1 in dioxane is EPR silent
consistent with its dimeric low-spin configuration
the EPR spectrum showed a distinct signal characteristic of a metal-based radical
which would be in line with our above calculations and proposed pathway
To test the wider synthetic potential of the isomerization
we set out to examine alternative vinylcyclopropane motifs
Variation of the aromatic-substituents had no marked impact; isomerization was equally rapid (5 min
yielding approximately 90:10 trans:cis selectivity with 82–98% yield with methoxy (2)
alkyl (5–6) or trifluoromethyl-substitution (7) as well as heterocyclic motifs
such as a benzofuran-substituted vinylcyclopropane (9)
The same final cis:trans ratio resulted irrespective of whether the exclusive cis-isomer or a cis/trans mixture was subjected to isomerization
vinylcyclopropyl ketones (aromatic and aliphatic
amides (21–22) as well as Weinreb amides (23) also isomerized efficiently to the corresponding trans-products in high selectivity and yield
albeit under slightly longer reaction times of 15 min to 2 h at room temperature
Even the free carboxylic acid was well tolerated and delivered 17 within 15 min at room temperature using 5 mol% of catalyst 1
purification was achieved by straightforward filtration
we envisioned that the straightforward construction of these building blocks as cis/trans mixtures
followed by Ni(I)-catalysed enrichment to the trans-isomer would be of value
albeit under slightly more forced conditions (60 °C and/or extended reaction time)
Capitalizing on the rich stereospecific diversification chemistry of the boronic ester unit can thus allow formation of substituted trans-vinylcyclopropanes with rests that might either be incompatible with Ni(I) catalysis or for which the inherent cis/trans stability difference of the substrate itself may not allow discrimination or induced selectivity in the reversible Ni(I)-catalysed isomerization process
this is the case for alkyl substituted versions
for which only bulky substituents (20) deliver high trans-thermodynamic preference and selectivity
35–36) and higher substitution at the cyclopropane ring (18
the starting material was fully recovered (27)
The scalability of the process was next examined
we employed 1 g of cyclopropane 16; since it is a liquid
we omitted any solvent and attempted the isomerization of the neat compound
adding solely 0.5 mol% of Ni(I) catalyst 1
a 92:8 trans:cis mixture of 16 was generated and isolated in 93% yield
Neither additives nor solvent nor heating were necessary
only minute amounts of the non-precious Ni(I) metalloradical was required and full atom-economy was retained in the process
Scope of isomerization of internal alkenyl cyclopropanes
To further harness the reversibility of the isomerization
its unique capability to retain stereochemical information and its exceptional mildness
we next considered to extend our studies to divinylcyclopropanes
We considered the identified mechanistic features an ideal match to facilitate this strategic transformation
as the reversible nature of the Ni(I)-based isomerization should cause any formed cis-1,2-divinylcyclopropane to undergo stereospecific Cope-type rearrangement and hence be removed from the equilibrium
the first counter-thermodynamic trans-to-cis isomerization of a divinylcyclopropane under retention of enantiopurity should result
followed by Cope-type rearrangement to generate the enantiomerically pure product
Enantiopure synthesis of (+)-dictyopterene C′
Loss of stereochemical information in thermal isomerization/Cope sequence
Application to fused bicyclic scaffolds (c) and spirocycles (d)
bDeprotection conditions: tetra-n-butylammonium fluoride (five equivalents)
The same process was equally effective with a larger ring (47) or one containing heteroatoms (48–50)
this report disclosed the distinct reactivity of a Ni(I)-metalloradical
in contrast to organic free radicals or many closed-shell metal catalysts
does not lead to ring opening of a (di)vinylcyclopropane under strain release but instead triggers its reversible isomerization under selective inversion of a single (stereo)centre under mild conditions
In light of the pronounced prevalence of odd-oxidation states in non-precious metal species
this study further manifests their potential to enhance the synthetic toolbox and to meet global demands for greater sustainability and lower energy usage in chemical processes
The authors declare that the data supporting the findings of this study are available within the paper and its Supplementary Information
in Transition Metal‐Catalyzed Carbene Transformations (eds Wang
Catalytic cascade reactions by radical relay
Carbene radicals in transition-metal-catalyzed reactions
Calibration of a new horologery of fast radical clocks
Ring-opening rates for ring- and α-alkyl-substituted cyclopropylcarbinyl radicals and for the bicyclo[2.1.0]pent-2-yl radical
(eds) Radicals in Organic Synthesis (Wiley
Recent applications of the divinylcyclopropane–cycloheptadiene rearrangement in organic synthesis
Radical redox-relay catalysis: formal [3+2] cycloaddition of N-acylaziridines and alkenes
Anti-Markovnikov alcohols via epoxide hydrogenation through cooperative catalysis
Highly asymmetric intramolecular cyclopropanation of acceptor-substituted diazoacetates by Co(II)-based metalloradical catalysis: Iterative approach for development of new-generation catalysts
Asymmetric radical bicyclization of allyl azidoformates via cobalt(II)-based metalloradical catalysis
in Small Ring Compounds in Organic Synthesis VI (ed
From discovery to application: 50 years of the vinylcyclopropane–cyclopentene rearrangement and its impact on the synthesis of natural products
Asymmetric preparation of polysubstituted cyclopropanes based on direct functionalization of achiral three-membered carbocycles
General cyclopropane assembly by enantioselective transfer of a redox-active carbene to aliphatic olefins
Nucleophilic carbenes derived from dichloromethane
Stereodivergent rhodium(III)-catalyzed cis-cyclopropanation enabled by multivariate optimization
The racemization of trans-1,2-divinylcyclopropane
Stereochemistry of the thermal isomerizations of trans-1-ethenyl-2-phenylcyclopropane to 4-phenylcyclopentene
in Patai’s Chemistry of Functional Groups (ed
Reversible homolysis of a carbon–carbon σ-bond enabled by complexation-induced bond-weakening
Cyclopropane stereomutation catalyzed by one-electron oxidants
Light-enabled deracemization of cyclopropanes by Al-salen photocatalysis
Photochemically induced ring opening of spirocyclopropyl oxindoles: evidence for a triplet 1,3-diradical intermediate and deracemization by a chiral sensitizer
Gold(III)-catalysed cis-to-trans cyclopropyl isomerization
Stereoselective cis-vinylcyclopropanation via a gold(I)-catalyzed retro-Buchner reaction under mild conditions
Synthesis of trienes by rhodium-catalyzed assembly and disassembly of non-acceptor cyclopropanes
Rhodium(I) catalysis of vinylcyclopropane epimerization and ring cleavage rearrangements
Highly active nickel catalysts for the isomerization of unactivated vinylcyclopropanes to cyclopentenes
Catalytic C–C bond activations via oxidative addition to transition metals
Transition metal chemistry of cyclopropenes and cyclopropanes
Transition metal-catalyzed selective C-C bond cleavage of vinylcyclopropanes in cycloaddition reactions
E-Olefins through intramolecular radical relocation
Monomeric three-coordinate N-heterocyclic carbene nickel(I) complexes: synthesis
and catalytic applications in cross-coupling reactions
Mechanism of the Ni(0)-catalyzed vinylcyclopropane–cyclopentene rearrangement
Comproportionation and disproportionation in nickel and copper complexes
Enantiospecific sp2–sp3 coupling of secondary and tertiary boronic esters
Tailor-made α-amino acids in the pharmaceutical industry: synthetic approaches to (1R,2S)-1-amino-2-vinylcyclopropane-1-carboxylic acid (vinyl-ACCA)
Thermal rearrangement of functionalized 1,2-divinylcyclopropane systems
A convenient synthesis of substituted 4-cyclohepten-1-ones
Preparation and thermal rearrangement of trans-3-[1-methyl-2-(2-methyl-1-propenyl)cyclopropyl]-2-cyclohexen-1-one
An efficient method for the annelative formation of functionalized cycloheptanes
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We thank Rheinisch-Westfälische Technische Hochschule (RWTH) Aachen University
the European Research Council (ERC-864849)
the DFG (German Research Foundation) Cluster of Excellence 2186 (The Fuel Science Center; ID: 390919832)
the German Merit Foundations (scholarship to M.M.) and the Fonds der Chemischen Industrie (Kekulé scholarship to T.M.K.) for funding
Calculations were performed with computing resources granted by Jülich Aachen Research Alliance-High Performance Computing (JARA-HPC) from RWTH Aachen University under project no
Bhaskar Mondal & Franziska Schoenebeck
All authors analysed the data and contributed to the preparation of the manuscript
The authors declare no competing interests
Nature thanks the anonymous reviewers for their contribution to the peer review of this work
Publisher’s note Springer Nature remains neutral with regard to jurisdictional claims in published maps and institutional affiliations
This file contains Supplementary Sections 1–15 – see Contents page for details
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a former curator at the Milwaukee Public Museum
and others collected these eggs from the 1870s into the early 1900s
and habitat notes were recorded for most species
Joseph's Provincial Convent and later pastor at St
Joseph would be the best curators of the egg collection
Joseph's Academy in 1923 and was cared for by Sister Mary Alexia
Sister Alexia compiled a catalog of the egg collection from Schoenebeck's original notes
Joseph's donated the egg collection and specimens of mounted birds to the Museum of Natural History in 1970
The eggs remained in their original cotton-filled boxes until 1995 when they were moved to the current exhibit.
These cases contain selected examples from a large historically significant pan-North American egg collection displaying 768 specimens
The collection also includes examples from Africa
This display consists of three newly constructed cases arranged by family and includes rare or extinct varieties such as Passenger Pigeon
Associated specimens collected in concert with the eggs include complete nests and multiple mounted examples of the bird species themselves
These specimens are curated for research within the Ornithological collection
Back
We are delighted to announce that the 2024 Thieme–IUPAC Prize has been awarded to Franziska Schoenebeck of RWTH Aachen University
Professor Schoenebeck becomes the 16th recipient of the prize
and joins a distinguished group of scientists whose research has had a major impact on the field of synthetic organic chemistry
which is awarded every two years and includes an award of € 5000
will be presented to Franziska Schoenebeck at the ICOS-24 conference before her Thieme–IUPAC lecture
Schoenebeck and look forward to hearing about the latest developments from her laboratories
Franziska Schoenebeck is leading an internationally recognized research program at the interface of organic synthesis
and physical organic chemistry and uniquely combines a cutting-edge synthetic organic chemistry program with state-of-the-art computational and mechanistic studies
Her group has made pioneering contributions in diverse areas such as the use of organogermanes in synthesis and catalysis
the development of efficient methods for the trifluoromethylation of nitrogen groups
and the application of machine learning in the study and development of dinuclear metal complex catalysts
Read more about her research
At thieme.de, see original announcement | read more about the prize | check out previous winners
< Originating Call for Nominations (1 Oct 2023)
Announcement published in the July 2024 issue of Chem Int
April 2025 update: The Prize will be presented to Franziska Schoenebeck at the ESOC 2025 before her award lecture
The 23rd European Symposium on Organic Chemistry will be in Copenhagen
Apply Now
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Sarita Yardi Schoenebeck ’02 recently received a grant from the National Science Foundation to study how kids use social media—and how parents can prepare them for life online
Currently an assistant professor in the School of Information at the University of Michigan
the California native majored in computer engineering at Dartmouth
where she earned women’s tennis First Team All-Ivy honors three times
She earned a master’s from UC Berkeley and a PhD from Georgia Tech
Schoenebeck ’02 spoke with From the GREEN about her work
“We know to teach children to brush their teeth and eat healthfully
but parents really don’t know how to teach online behavior
I study whether parents’ anxieties match children’s actual online behaviors
and design applications that help the whole family set expectations for social media use
and communicate with your children about technology
Do they understand the impact of what they’re sharing
Join Instagram or Snapchat or other sites your kids use
Everyone might agree not to use a cell phone at the dinner table—including Mom and Dad
but even now he watches when I’m on my laptop
Another research interest is what parents themselves are doing online—how are they moderating their own behavior
“My favorite thing about Dartmouth was the people—friends I made in engineering and the tennis team absolutely transformed me in terms of showing me how to prioritize relationships and balance my career.”
We inspire students to practice good global citizenship while strengthening their own communities
Act Now
Clem Schoenebeck saw his first granddaughter
in her mother's arms shortly after she was born
She and Kristen were staring into each other's eyes with such intensity a voice came to him in a transcendent moment of grace
He was completely taken with mystery and wonder
He was so moved he wrote a "letter of welcome" for his first grandchild
encouraged him to write the letter on his best stationary and frame it as a gift for his daughter
and she saw the possibilities of poetry in those written words
Clem signed up for poetry workshops given by Lynn's Jeanette Maes
one of his dental patients became significant in Schoenebeck's introduction to poetry
Must walked him through the process of submitting his first poem for publication
Clem was off and running with his new interest
His education continues today with Claire Keyes
professor emeritus of Salem State University
she runs a monthly poetry salon in Abbot Public Library
He has also been a long-time member of Swampscott’s monthly poetry group
They have been supportive and very special friends to each other
Clem has had poems published in nine or 10 different journals
He has had four nominations for The Pushcart Prize in Poetry
Encircle Publications puts out a highly respected journal
in which most of his published poems appeared
Encircle Publications also put out a collection of 100 of his poems: “Where the time went; poems at eighty.” This book was nominated for the Massachusetts Book Award for Poetry
Schoenebeck's father immigrated to the Boston area from Germany in 1923
He found his way to Holy Trinity Church on Shawmut Avenue in Boston
A priest from his hometown in Germany welcomed him and gave him a place to stay
in exchange for his work as a custodian for the church
Clem's father went to night school where he learned his new language
where he learned to be a highly skilled machinist
who was one of fourteen children of parents who also emigrated from Germany in 1903
Her oldest sister died in the Spanish Flu Epidemic of 1918
His father was hired to run the machine shop in the College of Mineral Sciences State and developed an outstanding reputation for building instruments for the scientists
He taught Clem and his two younger brothers
to be patient with any project they undertook
His father's words echo today: "If it's worth doing
Clem attended Penn State and joined the university’s track and cross country teams
Bonnie also attended Penn State as a psychology major
They were married during Clem's senior year at Tufts Dental School
This was followed by a two-year stint in the Army Dental Corps at Fort Ord in California
Upon completion of his military obligation
He opened his family practice in Swampscott in 1966
he was invited into a highly-respected group practice in Lynn
where he continued his work until his retirement 38 years later
He considers himself fortunate to have worked with some of the most outstanding people in his profession
Being invited to the Marblehead Writers’ Group opened Clem's imagination to a very meaningful event in his life
he published "Dancing with Fireflies," a memoir about growing up with his schizophrenic mother
He and his young brothers learned significant life lessons
in trying to dance around the lengthening shadows of his mother's mental illness
Poetry has been the gift that brought that awareness into full daylight
Clem is grateful for the blessed life he enjoys
Poetry has slowed him down in contemplation of words and what they mean
Trying to keep the words "truthful" as Jeanette Maes reminded him
LUXEMBURG (WLUK) --Luxemburg-Casco is playing in its first state championship football game after senior Trace Schoenebeck drilled a 24-yard field goal in the final seconds of a Division 4 Level 4 playoff win over Catholic Memorial
It was the most important play in program history and has made the 2023 season unlike any other
we won," Schoenebeck said as to what he was thinking before the kick
"So right before the kick I kind of zoned out and everything went quiet in my head and I was focused
I knew right away it was going in," said senior Max Ronsman
"I was probably one of the first ones celebrating
Funny thing about the game-winning kick is Ronsman was the holder
He actually let go of the football before it was kicked
it stayed upright andSchoenebeck did the rest
"Let go of it really early right before he kicked it; hand was not on the ball and it was still standing up," Ronsman said
That kick allowed L-C (12-1) to record its second straight "upset" of the postseason against a team in Catholic Memorial that was the favorite from the start of the season to win the state title.Schoenebeck's heroics followed a road win over Two Rivers
The Spartans have showed they are a championship-caliber team and now face Lodi (13-0) in the D4 state title game Thursday at 7 p.m
where they are probably viewed as the underdog again
we've played some really tough teams and some tough adversity
so I feel like we gave our best shot," coach Neil Seering said of the his team
And now Luxemburg-Casco gets to play at Camp Randall Stadium
with a seating capacity of more than 80,000
Seering has never patrolled the sidelines for a game at Camp Randall
"I remember being there as a spectator
but it will seem like nobody is there because it's so big and massive," he said
it's kind of a 'Hoosiers' idea for me
it's a night game at seven o'clock
look at your fans and embrace that and then get ready to play some Spartan football."
Win or lose Spartan football has made 2023 a season to remember
Metrics details
Cross-coupling is a catch-all term for reactions in which two prefunctionalized fragments — most often one halide or pseudohalide and one organometallic or organometalloid — are joined with the aid of a metal catalyst to form a new bond
Palladium-catalysed cross-coupling reactions in particular have revolutionized synthetic chemistry
These reactions are now such a well-established synthetic tool that it is difficult to imagine how we would synthesize many of the molecules of the modern world without them
Franziska Schoenebeck and co-workers from RWTH Aachen University have added a new orthogonal cross-coupling reaction to the toolkit: gold-catalysed cross-couplings of aryl germanes with diazoarenes
The work began with a detailed experimental and computational study of Pd-based chemistry
This revealed a fundamental problem: the transmetalation reaction at typical Pd(II) intermediates was highly endergonic — there was no driving force for the reaction — and the transition state was prohibitively high
unlike their homogeneous catalyst counterparts
catalysed cross-coupling of germanes and did so in preference to silanes
boronic acids or boronic esters,” says Schoenebeck
This observation as well as detailed computational studies led to the conclusion that germanes react preferentially in electrophilic aromatic substitution-type processes
“This explains why an electrophilic metal catalyst such as a cationic palladium nanoparticle was effective and
led us to try coupling using a gold catalyst,” she continues
Prices may be subject to local taxes which are calculated during checkout
Sherborne, G. J. et al. Modular and selective arylation of aryl germanes (C–GeEt3) over C–Bpin, C–SiR3 and halogens enabled by light-activated gold catalysis. Angew. Chem. Int. Ed. https://doi.org/10.1002/anie.202005066 (2020)
Gold-catalyzed C–H functionalization with aryl germanes
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Nature Reviews Chemistry http://www.nature.com/natrevchem/
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DOI: https://doi.org/10.1038/s41570-020-0207-y
actress Angelina Jolie shocked the world with her announcement she had a double mastectomy
Her mother died of breast cancer in 2007 and
Jolie carried a genetic mutation that put her at an increased risk for developing various cancers
The procedure — and a subsequent ovary and a fallopian tube removal — were done to reduce her risk
I remember being inspired by all of this for two reasons
Jolie helped reignite a dialogue about a serious women's health issue that for so long had been taboo
can be a powerful tool for those predisposed to the disease
senior genetic counselor at Aurora BayCare Medical Center
the process of genetic testing is one that should come with consideration
as results could yield either good or bad news — although that perception varies from patient to patient.
"It's my job to basically lay out the positives and negatives and help people understand how this information can benefit their health," she said. "Regardless, I make sure they're comfortable with their choice."
would I want to know if I had a gene that meant I was at a high risk for disease
was one of Schoenebeck's first cardiology genetic counseling patients when the medical center began offering counseling to cardiology patients just last year. Guilfoyle is another example of a woman who despite facing tough circumstances, decided to dive into the unknown and take control of her health and future like never before.
Guilfoyle underwent genetic counseling in October to determine her risk for hypertrophic cardiomyopathy — a potentially deadly condition in which the heart muscle becomes abnormally thick
making it harder for the heart to pump blood.
Guilfoyle said she sought out genetic counseling through guidance and support form her mother who revealed a number of family members had been diagnosed with the heart condition. Guilfoyle said the realization
uncles and others endured things likes shortness of breath
need for a pacemaker and even cardiac arrest.
After learning of Guilfoyle's family history and her desire to know her risk for the heart condition
an interventional cardiologist at Aurora Baycare, ordered an echocardiograph and a blood test.
Guilfoyle's test results came back positive for the MYH7 gene which means there's a higher chance that she might someday be diagnosed with hypertrophic cardiomyopathy.
I was hoping there wasn't going to be a genetic mutation," she said "I'm going to say it was bittersweet
Just having those results and knowing my identity in that sense
I'm the owner and operator of my life and it might not come with a how-to manual
The news wasn't what she wanted to hear, but the good thing is she didn't have to change much about her lifestyle.
massage therapist and lover of the performing arts
avoiding stress and maintaining a healthy blood pressure
If a patient is diagnosed with the condition
could require surgery or a heart transplant
Whatever the future holds, Guilfoyle said, "I am not going to dwell on this hurdle."
back to the question: If my family members were diagnosed with a disease
would I want to know if I had a genetic mutation that predisposes me to it
The benefits of knowing seem to outweigh the bad news factor
The scenarios are either I learn I don't have a mutation, I learn I do and take it in stride
or the diagnosis is devastating and drastically alters the rest of my life.
The truth is, I don't know what I'd do. And I'll likely never know what I'd do unless I'm actually put in this situation. But this is exactly why genetic counselors exist — to help all kinds of patients make important decisions just like Guilfoyle did.
GREEN BAY – It’s been 48 years since a Green Bay East football team had an undefeated season
Members of the 1969 team who accomplished the feat gathered on Friday at the Rite Place for a long overdue reunion
The group went 8-0 that season and finished as the third-ranked team in the state while playing for legendary coach Gene Bray
“I think you kind of reach a point where people are starting to retire and you reflect on those fun years
those special years,” said Dennis Schoenebeck
“Although it was only an eight-game season
the Red Devils didn’t have a bunch of big-name players that season despite their lofty ranking
who went on to play tight end at Illinois and now is the CEO of Global Benefits Group Insurance in California
But what the Red Devils did have was a nasty defense
After beating rival Green Bay West in a season opener – it was the first time in the historic series the teams met in September – East put together five straight shutouts on its way to a perfect season
Schoenebeck was on a defensive line that included Bruce Steinfeldt
Ken Kox and Steve Schuh were the team’s top linebackers
while Dubrish led a secondary that included Steve Keuler
“We had a very special group of guys that were talented
but also it was probably the most unselfish group of guys I ever played with,” said Steinfeldt
who played one season at the University of Wisconsin-La Crosse and worked in the press room at the Green Bay Press-Gazette for 26 years
some of the Red Devils always have wondered what could have been during an era when there was no postseason play
The WIAA didn’t sponsor a state football playoff program until 1976
East didn’t get an opportunity to face top-ranked Fond du Lac or second-ranked Antigo
East and Fond du Lac shared the Fox River Valley Conference title in the 12-team league
“We just felt we got robbed,” Steinfeldt said
“The one year we didn’t play Fond du Lac.”
Fond du Lac had several standout players that season
including a handful who earned Division I scholarships
“We would have liked to play them to see what happens,” said kicker and offensive lineman Bob DeKeyser
“Our mindset was that we would beat them
You just couldn’t think any other way.”
Although there was no state championship to celebrate
there is a certain amount of pride still felt for what the team helped start
That squad started a run of 30 wins in 35 games the next four seasons and put Bray on his eventual path to the Wisconsin High School Football Coaches Association Hall of Fame in 1989
Bray coached at East from 1967 to 1982 and went 87-48-3 while leading the Red Devils to six FRVC titles
“We had something going on there that was a little bit special,” DeKeyser said
“We always felt that the ’69 class was Bray’s only undefeated team
and we kind of felt that maybe our class was the class that started that era of really good East football."
There also can be pride that so many of the players did well after high school
some of which can be attributed to Bray and a coaching staff that included Robert Boyle
Schoenebeck came from a single-parent family and wasn’t sure what he should do with his life after high school
Bray approached him and told his pupil he expected him to attend college
Those few words gave Schoenebeck the encouragement to move in that direction
He retired in January 2016 after serving as the CEO of the Greater Wichita YMCA in Kansas for 25 years
“I have to credit him for going to school,” Schoenebeck said of Bray
DeKeyser also wasn’t sure if he wanted to attend college
He had a summer job with Schreiber at the time
But the coaching staff sat him down and asked about his classes
Boyle took him out of practice and brought him to the guidance office to fill out a scholarship form
DeKeyser was a standout kicker at UW-Platteville because that’s where Bray urged him to go
He ended up setting every kicking record in the program’s book
earned a Master’s degree and was a school counselor until retiring 10 years ago at 55
Norbert the past 19 seasons and also had coaching stints at Platteville and in the high school ranks at Niagara
“How much more of a defining role can someone have on your life?” DeKeyser said of his coaches
there is a lot of opportunities to go astray
all those kinds of guys were there to grab you by the ear and say
‘This is what you are going to do.’ I know they did that for a lot of guys
“So much of my life would have been different without those guys.”
Swampscott resident Clem Schoenebeck will be at the Swampscott Public Library on Thursday
He will be reading excerpts from his book “Where the Time Went: Poems at Eighty.”
The book was recently nominated for the Massachusetts Book Award for Poetry
and the Foreword INDIES Book of the Year Award
Schoenebeck will read his poem “Flight,” which is dedicated to Jennifer Harris
a Swampscott resident who died in service to her country
A copy of it will be framed and hung near Jennifer’s portrait in the library’s Harris Room
Registration for this event will begin on Monday
Please register from the library website at www.swampscottlibrary.org
A bright blue swimming pool stands out amid murky floodwater from the River Elbe
which swamped this garden near the German city of Magdeburg during floods that swept through a huge area of Europe
The deluge forced thousands of people to flee their homes in Germany
the Czech Republic and Hungary and caused billions of dollars of damage
A man inspects a sandbag wall near the River Elbe in the eastern German town of Schoenebeck
Flooded railway tracks are pictured near the River Elbe in the eastern German town of Schoenebeck
A dead deer hangs on a fence along the flooded A3 motorway near Deggendorf
A car drives away from a small settlement flooded by the River Danube near Deggendorf
Volunteers relax on a wall of sandbags put up to contain damage caused by flooding in Dresden
Two men paddle their boat into the entrance of a flooded house
A brand new Jaguar F-Type convertible stands in a showroom covered with a thin film of mud following the deluge
The statue of world harmony leader Sri Chinmoy is partially submerged by the rising Vltava River
A man checks the water level of the swollen Vltava River
Firemen pump water out of a flooded field near the city of Melnik
People walk over Radobyl Hill to look at an area flooded by the swollen Labe (Elbe) River
A girl from the village of Mlekojedy stands with her dog in front of the flooded road to her home
Firefighters evacuate a woman from her house in the southern Bohemian village of Nemcicky
Vaclav Reichl dries out his family photographs
The door of a house is almost totally submerged in the village of Lounky
Waters overflow from the River Danube in Bratislava
A man in a boat floats along a street flooded by the River Danube in Klosterneuburg
Gravestones are partially submerged by flood water at a cemetery in Schaerding
A church stands partially underwater in Marbach
A priest leaves a church with sandbags arranged around the entrance in Budapest
A ticket booth for cruise ships stands mostly underwater along the banks of the flooding River Danube
Houses near the Hungarian town of Nagymaros are surrounded by floodwater from the River Danube
Before: A man sweeps steps by the banks of the River Danube before it flooded in Budapest.After: A few days later
Before: People walk along the edge of the swollen Vltava River in Prague.After: Twenty-four hours later
Before: Water floods a soccer field south of the Bavarian city of Deggendorf.After: The same field is seen after the deluge receded
By Donna Lu
French bulldogs can have breathing problems
Many English and French bulldogs develop breathing difficulties
and the flat faces of these breeds have long been thought to be responsible
but now a gene mutation in these dogs suggests that face shape isn’t the only culprit
Jeffrey Schoenebeck at the University of Edinburgh
and his colleagues have found a mutation in a gene called ADAMTS3
Norwich terriers often suffer from similar breathing problems even though they have proportional noses
The team analysed DNA from more than 400 Norwich terriers